answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
Lina20
3 months ago
12

66.667 mL of 3.000 M H2SO4 (aq) solution was neutralized by the stoichiometric amount of 4.000 M Al(OH)3 solution in a coffee cu

p calorimeter. The initial temperature of the solutions was 22.3 C and after mixing the temperature raised to 24.7 C. If the heat capacity of the coffee cup is 1.10 J/g C, calculate the delta H reaction in J/mol Al2(SO4)3
Chemistry
1 answer:
eduard [2.7K]3 months ago
6 0

Answer:

\large \boxed{\Delta_{\textbf{r}}H =\text{-4600 J$\cdot$ mol}^{-1}}

Explanation:

This scenario is unrealistic since Al(OH)₃ is not soluble in water.

The question consists of two parts:

A. Stoichiometry — where we determine volumes, masses, and moles for the products

B. Calorimetry — where we assess the enthalpy of the reaction.

A. Stoichiometry

1. Determine the volume of Al(OH)₃

(a) The balanced chemical equation:

                 2Al(OH)₃ + 3H₂SO₄ ⟶ Al₂(SO₄)₃ + 6H₂O

M/V:            66.667

c/mol·L⁻¹:   4.000       3.000

(b) Moles of H₂SO₄

\rm \text{66.667 mL H$_{2}$}SO_{4} \times \dfrac{\text{3.000 mmol H$_{2}$SO}_{4}}{\text{1 mL H$_{2}$SO}_{4}} = \text{200.00 mmol H$_{2}$SO}_{4}

(c) Moles of Al(OH)₃

The molar ratio stands at 2 mmol Al(OH)₃: 3 mmol H₂SO₄

\text{Moles of Al(OH)}_{3} = \text{200.00 mmol of H$_{2}$SO}_{4} \times \dfrac{\text{2 mmol Al(OH)}_{3}}{\text{3 mmol H$_{2}$SO}_{4}}\\\\= \text{133.33 mmol Al(OH)}_{3}

(d) Volume of Al(OH)₃

\text{Moles of Al(OH)}_{3} = \text{200.00 mmol of H$_{2}$SO}_{4} \times \dfrac{\text{1 mL Al(OH)}_{3}}{\text{4 mmol H$_{2}$SO}_{4}} = \text{50.000 mL Al(OH)}_{3}

B. Calorimetry

This reaction has two energy exchanges.

q₁ = heat from the reaction

q₂ = heat used to heat the calorimeter

 q₁ + q₂ = 0

nΔH + mCΔT = 0

Data:

Moles of Al₂(SO₄)₃ = 0.066 667 mol

C = 1.10 J°C⁻¹g⁻¹

T_initial = 22.3 °C

T_final = 24.7 °C

Calculations

(a) Mass of solution

Assume solutions are as dense as water (though not realistic).

Mass of sulfuric acid solution            =   66.667 g 

Mass of aluminium hydroxide solution =  50.000    

                                             TOTAL =  116.667 g

(b) ΔT

ΔT = T_final - T_initial = 24.7 °C - 22.3 °C = 2.4°C

(c) ΔH

\begin{array}{ccccl}n\Delta H & +& mC \Delta T& = &0\\\text{0.066 667 mol }\times \Delta H& + & \text{116.667 g} \times 1.10 \text{ J$^{\circ}$C$^{-1}$g$^{-1}$} \times 2.4 \, ^{\circ}\text{C} & = & 0\\0.066667 \Delta H \text{ mol} & + & \text{310 J} & = & 0\\&&0.066667 \Delta H \text{ mol} & = & \text{-310 J} & & \\\end{array}\\

\begin{array}{ccccl}& &\Delta H & = & \dfrac{\text{-310 J}}{\text{0.066667 mol}}\\\\& &\Delta H & = & \textbf{-4600 kJ/mol}\\\end{array}\\\large \boxed{\mathbf{\Delta_{\textbf{r}}H} =\textbf{-4600 J$\cdot$ mol}^{\mathbf{-1}}}

This result appears nonsensical, but it is derived from your given figures.

You might be interested in
How can a piece of wood floating on water illustrate the condition of lowest potential energy and maximum
Tems11 [2777]

Answer:

By reducing the height of the center of gravity of the object in relation to its center of buoyancy

Explanation:

In the field of hydrostatics, for a floating object, the state of equilibrium corresponds to either a peak or a trough in potential energy. Stability in equilibrium occurs when the potential energy is minimized. Achieving a lower position of the center of gravity of the floating object compared to its center of buoyancy creates a stable equilibrium arrangement.

4 0
4 months ago
A geological sample is found to have a Pb-206/U-238 mass ratio of 0.337/1.00. Assuming there was no Pb-206 present when the samp
eduard [2782]

Answer:

2.1 times 10 to the power of 9 years

Explanation:

U-238 is a radioactive isotope that emits particles as it decays. This results in a reduction of its mass, converting it into Pb-206.

The duration required for a substance to lose half of its mass is defined as its half-life. By knowing both the initial mass (mi) and the resulting mass (m), the number of half-lives that have occurred (n) can be calculated using the following equation:

m = mi divided by 2 raised to the power of n

The mass of Pb-206 corresponds to the mass that U-238 has lost, thus it can be expressed as mi - m. Consequently, the mass ratio can be represented as:

(mi - m) divided by m = 0.337 divided by 1

mi - m = 0.337m

mi = 1.337m

Inserting mi into the half-life equation gives:

m = 1.337m divided by 2 raised to the power of n

2 raised to the power of n = 1.337m divided by m

2 raised to the power of n = 1.337

ln(2 raised to the power of n) = ln(1.337)

n multiplied by ln(2) = ln(1.337)

n = ln(1.337) divided by ln(2)

n = 0.4190

The elapsed time (t), or the approximate age of the sample, is calculated by multiplying the half-life duration by n:

t = 4.5 times 10 to the power of 9 multiplied by 0.4190

t ≈ 1.88 times 10 to the power of 9 years, which is approximately 2.1 times 10 to the power of 9 years.

5 0
3 months ago
First-order reaction that results in the destruction of a pollutant has a rate constant of 0.l/day. (a) how many days will it ta
Alekssandra [3086]

The rate equation for a first order reaction can be expressed as follows:

t=\frac{2.303}{k}log\frac{A_{0}}{A_{t}}

In this context, k represents the reaction's rate constant, t denotes the time the reaction takes, A_{0} is the initial concentration, and A_{t} is the concentration at time t.

The rate constant of the reaction is 0.1 day^{-1}.

(a) If we start with an initial concentration of 100, when 90% of the substance is eliminated, the remaining quantity at time t will be 100-90=10. By substituting the values,

t=\frac{2.303}{k}log\frac{A_{0}}{A_{t}}=\frac{2.303}{0.1 day^{-1}}log\frac{100}{10}=23.03 days

The time required to destroy 90% of the substance amounts to 23.03 days.

(b) If the initial concentration is set at 100, when 99% is destroyed, the present amount at time t will be 100-99=1. By substituting the input values,

t=\frac{2.303}{k}log\frac{A_{0}}{A_{t}}=\frac{2.303}{0.1 day^{-1}}log\frac{100}{1}=46.06 days

This results in a duration of 46.06 days required to eradicate 99% of the chemical.

(c) Should the initial concentration be set at 100, with 99.9% of the chemical removed, the remaining quantity at time t will be 100-99.9=0.1. Substituting the values yields

t=\frac{2.303}{k}log\frac{A_{0}}{A_{t}}=\frac{2.303}{0.1 day^{-1}}log\frac{100}{0.1}=69.09 days

Thus, the time needed to eliminate 99.9% of the chemical is calculated as 69.09 days.

5 0
3 months ago
Other questions:
  • Enter the net ionic equation representing solid chromium (iii) hydroxide reacting with nitrous acid. express your answer as a ba
    14·2 answers
  • (g) On the graph in part (d) , carefully draw a curve that shows the results of the second titration, in which the student titra
    14·1 answer
  • Which procedure cannot be performed on a hot plate, requiring a Bunsen burner instead
    6·1 answer
  • 4.One rubber tire can generate about250,000 BTUS (1BTU=.0003KW ) when it is burned. The average American home consumes about 10,
    5·1 answer
  • Which of the given statements are true of low molecular weight carboxylic acids? Low molecular weight carboxylic acids are volat
    12·1 answer
  • Consider the equilibrium reaction. 4A+B↽−−⇀3C After multiplying the reaction by a factor of 2, what is the new equilibrium equat
    6·1 answer
  • A gas sample at stp contains 1.15 g oxygen gas and 1.55 g nitrogen gas.what is the volume of the gas sample?
    8·2 answers
  • Be sure to answer all parts. What is the effect of each of the following on the volume of 1 mol of an ideal gas? (a) The pressur
    13·1 answer
  • A closed vessel system of volume 2.5 L contains a mixture of neon and fluorine. The total pressure is 3.32 atm at 0.0°C. When th
    11·1 answer
  • Two containers hold the same radioactive isotope. Container A contains 1000 atoms, and container B contains 500 atoms. Which of
    5·2 answers
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!