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LuckyWell
16 days ago
9

6.74 g of the monoprotic acid KHP (MW = 204.2 g/mol) is dissolved into water. The sample is titrated with a 0.703 M solution of

calcium hydroxide to the equivalence point. What volume of base was used?
Chemistry
1 answer:
eduard [2.5K]16 days ago
4 0

Answer:

The volume of calcium hydroxide solution utilized is 0.0235 mL.

Explanation:

2KHP+Ca(OH)_2\rightarrow 2H_2O+Ca(KP)_2

Moles of KHP = \frac{6.74 g}{204.2 g/mol}=0.0330 mol

In accordance with the reaction, 2 moles of KHP react with 1 mole of calcium hydroxide, thus 0.0330 moles of KHP will react with;

\frac{1}{2}\times 0.0330 mol=0.01650 mol of calcium hydroxide

The molarity of calcium hydroxide solution = 0.703 M

Volume of calcium hydroxide solution = V

Molarity=\frac{Moles}{Volume(L)}

0.703 M=\frac{0.01650 M}{V}

V=\frac{0.01650 M}{0.703 M}=0.0235 mL

The volume of the calcium hydroxide solution utilized is 0.0235 mL.

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Clarification:

The pertinent information is outlined as follows.

m = 10.0 kg = 10,000 g (since 1 kg = 1000 g)

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Starting temperature of block 2, T_{2} = 0^{o}C = (0 + 273) K = 273 K

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T_{f} = 50^{o}C

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   \Delta S_{2} = mC ln \frac{T_{f}}{T_{i}}

           = 10000 g \times 0.385 J/K g \times ln \frac{323}{273}

           = 10000 g \times 0.385 J/K g \times 0.168

           = 647.49 J/K

Thus, the total entropy is the sum of the entropy changes of both blocks.

                   = -554.12 J/K + 647.49 J/K\Delta S_{total} = \Delta S_{1} + \Delta S_{2}

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In conclusion, for this reaction, the outcome is 1243.5 kJ and \Delta S_{total} is 93.37 J/K.

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