To find the answer, start by calculating the total mass of the copper utilized:
Copper used = 100 pennies x 3.0g Cu per penny = 300.0 g Cu
Next, identify the path and molar ratios from Cu produced back to CuFeS2 needed using the established balanced reactions:
1 Cu2S from 2 CuS; 2Cu from 1 Cu2S; 2CuS from 2CuFeS2
Thus, 2Cu comes from 2CuFeS2, indicating a 1:1 molar ratio.
Then convert grams of Cu to moles and grams of CuFeS2:
= 300.0 g Cu * 1 mol Cu/63.546g Cu * 2 mol CuFeS2/2 moles Cu
= 4.72 moles CuFeS2
The required amount of chalcopyrite mined = 4.72 moles CuFeS2 * 183.54 g CuFeS2/1 mole
CuFeS2 = 866.49 g CuFeS2
The form of ossification that takes place is the endomembrane or endochondral type. In joints classified as SYNARTROSIS, there isn't an intermediate formation of ligament or cartilage, meaning the bone grows not from cartilage ossification but from undifferentiated cells that will calcify into bone cells, forming the primary structural units called OSTEONAS. The skull bones, particularly in the temporal region (Temporary Suture), exhibit this type of joint, which experiences rapid growth over a lifetime through mechanisms distinct from those affecting movable joints.
extinction coefficient (ε) = 347 L·mol⁻¹·cm⁻¹. The chemical equation representing the reaction of chromium (Cr) with hydrochloric acid (HCl) is: 2 Cr + 6 HCl → 2 CrCl₃ + 3 H₂. To find the number of moles, we apply the formula: number of moles = mass / molar weight. For chromium, we calculate: number of moles of Cr = 0.3 × 10⁻³ (g) / 52 (g/mole), leading to number of moles of Cr = 5.77 × 10⁻⁶ moles. Examining the reaction, we observe that 2 moles of Cr yield 2 moles of CrCl₃, hence 5.77 × 10⁻⁶ moles of Cr will also produce 5.77 × 10⁻⁶ moles of CrCl₃. The molar concentration is determined by: molar concentration = number of moles / volume (L), thus molar concentration of CrCl₃ = 5.77 × 10⁻⁶ / 10 × 10⁻³, which equals 5.77 × 10⁻⁴ moles/L. To convert percent transmittance (%T) to absorbance (A), we use the equation A = 2 - log(%T). Therefore, A = 2 - log(62.5), leading to A = 0.2. The relationship defining absorbance (A) includes the extinction coefficient (ε), path length (l), and concentration (c): A = εlc, hence ε = A / lc, giving ε = 0.2 / (1 × 5.77 × 10⁻⁴), which results in ε = 0.0347 × 10⁴. Thus, the extinction coefficient is ε = 347 L·mol⁻¹·cm⁻¹.