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Llana
2 months ago
6

75.0 g of PCl5(g) is introduced into an evacuated 3.00–L vessel and allowed to reach equilibrium at 250ºC. PCl5(g) ↔ PCl3(g) + C

l2(g) If Kp = 1.80 for this reaction, what is the total pressure inside the vessel at equilibrium (R = 0.0821 L·atm·K-1·mol-1)?
Physics
1 answer:
Softa [3K]2 months ago
6 0

Answer:

The cumulative pressure inside the container amounts to 7.42 atm

Explanation:

given information

Weight of PCl5 = 75 g

Volume V = 3L

Temperature T = 250ºC = 250 + 273 = 523 K

The reaction can be represented as: PCl5(g) ↔ PCl3(g) + Cl2(g)

Kp = 1.80

R = 0.0821 L·atm·K-1·mol-1

to determine

the overall pressure within the container

solution

it is known that the molar mass of PCl5 = 208.24 g/mol

thus, moles of PCl5 ( n )= 75 / 208.24 = 0.36 moles

and

the initial pressure of PCl5 = nRT /V

substituting the values

initial pressure of PCl5 = 0.36 (0.0821 )523 / 3

initial pressure of PCl5 = 5.149 atm

thus,[Kp = [PCl3(g)] × [Cl2(g)] / ( PCl5 )

and given

at equilibrium x atm of product

and the 5.149 - x atm of reactant here

we can formulate

1.8 = x² / ( 5.149 - x )

thus, x² +1.8 x - 9.267 = 0

x = 2.274429

here 2.274 atm stands for Cl2 + PCl3 pressure

therefore, the pressure from PCl5 becomes 5.149 - 2.274 = 2.875 atm.

so finally

total pressure equates to 2.87 + 2.27 + 2.27

the total pressure inside the container is found to be 7.42 atm

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Answer:

The rotational angular speed is measured at 1.34 rad/s.

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Considering the following parameters,

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Using the balance equation

Horizontal component

T\cos\theta=mg

T=\dfrac{mg}{\cos\theta}

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T\sin\theta=m\omega^2 r

Substituting the tension value

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Substituting the value into the equation

\omega=\sqrt{\dfrac{9.8\tan45.0}{5.90+3.40\sin45.0}}

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A merry-go-round with a a radius of R = 1.63 m and moment of inertia I = 196 kg-m2 is spinning with an initial angular speed of
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1) L = 299.88 kg-m²/s

2) L = 613.2 kg-m²/s

3) L = 499.758 kg-m²/s

4) ω₁ = 0.769 rad/s

5) Fc = 70.3686 N

6) v = 1.2535 m/s

7) ω₀ = 1.53 rad/s

Explanation:

Given

R = 1.63 m

I₀ = 196 kg-m²

ω₀ = 1.53 rad/s

m = 73 kg

v = 4.2 m/s

1) What is the magnitude of the initial angular momentum of the merry-go-round?

We utilize the formula

L = I₀*ω₀ = 196 kg-m²*1.53 rad/s = 299.88 kg-m²/s

2) What is the angular momentum magnitude of the person 2 meters prior to jumping onto the merry-go-round?

The equation we apply is

L = m*v*Rp = 73 kg*4.2 m/s*2.00 m = 613.2 kg-m²/s

3) What is the angular momentum of the person just before she hops onto the merry-go-round?

We utilize the formula

L = m*v*R = 73 kg*4.2 m/s*1.63 m = 499.758 kg-m²/s

4) What is the angular velocity of the merry-go-round after the individual jumps on?

We can apply the Principle of Conservation of Angular Momentum

L in = L fin

⇒ I₀*ω₀ = I₁*ω₁

where

I₁ = I₀ + m*R²

⇒  I₀*ω₀ = (I₀ + m*R²)*ω₁

At this point, we can determine ω₁

⇒  ω₁ = I₀*ω₀ / (I₀ + m*R²)

⇒  ω₁ = 196 kg-m²*1.53 rad/s / (196 kg-m² + 73 kg*(1.63 m)²)

⇒  ω₁ = 0.769 rad/s

5) Once the merry-go-round moves at this new angular speed, what force must the person exert to hold on?

We must calculate the centripetal force as follows

Fc = m*ω²*R  

⇒  Fc = 73 kg*(0.769 rad/s)²*1.63 m = 70.3686 N

6) When the person is halfway around, they choose to simply release their hold on the merry-go-round to exit the ride.

What is the linear speed of the person the moment they exit the merry-go-round?

we can apply the equation

v = ω₁*R = 0.769 rad/s*1.63 m = 1.2535 m/s

7) What is the angular velocity of the merry-go-round after the individual releases their hold?

ω₀ = 1.53 rad/s

It returns to its original angular speed

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