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d1i1m1o1n
3 months ago
12

What is the theoretical yield of aluminum that can be produced by the reaction of 60.0 g of aluminum oxide with 30.0 g of carbon

according to the following chemical equation? Al2O3 + 3C → 2Al + 3CO
Chemistry
1 answer:
Alekssandra [3K]3 months ago
3 0

Answer:

Theoretical yield = 31.8 g

Explanation:

The following formula is utilized to determine moles:

moles = \frac{Mass\ taken}{Molar\ mass}

For Al_2O_3

Mass of Al_2O_3  = 60.0 g

Molar mass of Al_2O_3  = 101.96128 g/mol

The mole calculation formula is once again provided here:

moles = \frac{Mass\ taken}{Molar\ mass}

Consequently,

Moles= \frac{60.0\ g}{101.96128\ g/mol}

Moles_{Al_2O_3}= 0.5885\ mol

Based on the provided reaction:

Al_2O_3+3C\rightarrow 2Al+3CO

1 mole of aluminium oxide reacts with 3 moles of carbon

0.5885 mole of aluminium oxide reacts with 3\times 0.5885 moles of carbon

Moles of carbon = 1.7655 moles

Available moles of carbon = 2.4978 moles

The limiting reagent is defined as the substance present in the smallest quantity. Hence, aluminium oxide serves as the limiting reagent.

The yield of the product is dictated by the limiting reagent. Thus,

1 mole of aluminium oxide results in the formation of 2 moles of aluminium.

0.5885 mole of aluminium oxide results in the formation of 2\times 0.5885 moles of aluminium.

Moles of aluminium = 1.177 moles

Molar mass of aluminium = 26.981539 g/mol

Mass of aluminium = Moles × Molar mass = 1.177 × 26.981539 g = 31.8 g

Theoretical yield = 31.8 g

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To determine the packing factor, begin by calculating the area and volume of the unit cell.

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In this case, R represents the radius and is connected to a as shown:

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Substituting the value into the area formula,[ [TAG_14]]

A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}

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Substituting the value,[ [TAG_27]]

Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}

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Given, there are 2 chromium atoms and 3 oxygen atoms, thus, the total units for chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii for Cr^{3+} and O^{2-} measure 62 pm and 140 pm respectively.

Transforming them into centimeters:

1 pm=10^{-10}cm

Therefore,

r_{Cr^{3+}}=6.2\times 10^{-9}cm

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r_{O^{2-}}=1.4\times 10^{-8}cm

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Thus, the atomic packing factor equals 0.758.

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