The correct answers are B and D. Explanation: Given the information presented, we have absorption bands at 3300 cm-1 and 2200 cm-1, indicating the presence of an alkyne functional group. Furthermore, the hydrogenation of the unknown compound utilizes two moles of hydrogen, which correlates with the two pi bonds found in the alkyne group. Hence, we can eliminate choices "a" and "e." Since hydrogenation yields 2-methylhexane, option c is also dismissed, given that the methyl group attaches at carbon 3. Therefore, structures b and d remain viable.
<span>The partial pressure of oxygen is 438.0 mmHg. The ideal gas equation is expressed as PV = nRT where P represents pressure, V denotes volume, n is the number of moles, R is the ideal gas constant (8.3144598 (L*kPa)/(K*mol)), and T signifies absolute temperature. To convert from Celsius to Kelvin, we have 43.4 + 273.15 = 316.55 K. For the pressure conversion from mmHg to kPa: 675.9 mmHg * 0.133322387415 = 90.11260165 kPa. When solving for n using the ideal gas equation, we derive n = PV / (RT) which provides n = 90.11260165 kPa * 16.2 L / (8.3144598 (L*kPa)/(K*mol) * 316.55 K)= 1459.824147 L*kPa / 2631.94225 (L*kPa)/(mol), resulting in n = 0.554656603 mol. Thus, we have 0.554656603 moles of gas particles. Next, we determine the contribution from oxygen. The atomic weight of oxygen is 15.999 g/mol, while argon is 39.948 g/mol, and the molar mass of O2 is 31.998 g/mol. We establish the relationships where M is the number of moles of O2, and 0.554656603 - M gives the number of moles of Ar. Setting up the equation: M * 31.998 + (0.554656603 - M) * 39.948 = 19.3, we solve for M resulting in 0.359424148 moles of oxygen out of 0.554656603 total moles. This leads to oxygen providing 0.359424148 / 0.554656603 = 0.648012024 or 64.8012024% of the total pressure of 675.9 mmHg. The partial pressure therefore calculates to 675.9 * 0.648012024 = 437.9913271 mmHg, rounded to 438.0 mmHg</span>
The L- isomer serves as the enantiomer of the D- isomer, and given that the optical rotation of the D- isomer is + 13.5°, the L- isomer's optical rotation will have the same magnitude but an opposite sign, resulting in -13.5°.
Thus, the rotation of the racemic mixture will be equal to 0°.
- This occurs because a racemic mixture contains equal proportions of both enantiomers.
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