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Anon25
1 month ago
9

An unknown compound, B, has the molecular formula C7H12. On catalytic hydrogenation 1 mol of B absorbs 2 mol of hydrogen and yie

lds 2-methylhexane. B has significant IR absorption band at about 3300 and 2200 cm-1. Which compound best represents B?
a. 5-methyl-1,3-hexadiene
b. 5-methyl-1-hexyne
c. 3-methyl-1-hexyne
d. 5-methyl-2-hexyne
e. 2-methyl-1,5-hexadiene

Chemistry
1 answer:
castortr0y [3K]1 month ago
5 0
The correct answers are B and D. Explanation: Given the information presented, we have absorption bands at 3300 cm-1 and 2200 cm-1, indicating the presence of an alkyne functional group. Furthermore, the hydrogenation of the unknown compound utilizes two moles of hydrogen, which correlates with the two pi bonds found in the alkyne group. Hence, we can eliminate choices "a" and "e." Since hydrogenation yields 2-methylhexane, option c is also dismissed, given that the methyl group attaches at carbon 3. Therefore, structures b and d remain viable.
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21.7 mL of gas at 98.8 kPa is allowed to expand at constant temperature into a 52.7 mL container. What is the new pressure of th
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The new pressure of the gas is calculated to be 40.7 kPa. Using the principle that P1 • V1 = P2 • V2, we can set 98.8 kPa (P1) multiplied by 21.7 mL (V1) equal to P2 (unknown pressure) multiplied by 52.7 mL (V2). To isolate P2, we rearrange the equation to P2 = (98.8 kPa • 21.7 mL) / 52.7 mL, resulting in P2 equal to 40.7 kPa.
8 0
2 months ago
The reaction between nitrogen dioxide and carbon monoxide is NO2(g)+CO(g)→NO(g)+CO2(g)NO2(g)+CO(g)→NO(g)+CO2(g) The rate constan
eduard [2782]

Response: The rate constant at 525 K is, 0.0606M^{-1}s^{-1}

Rationale:

Based on the Arrhenius equation,

K=A\times e^{\frac{-Ea}{RT}}

or,

\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_1 = rate constant when 701K = 2.57M^{-1}s^{-1}

K_2 = rate constant when 525K =?

Ea = activation energy for the process = 1.5\times 10^2kJ/mol=1.5\times 10^5J/mol

R = gas constant = 8.314 J/mole.K

T_1 = initial temperature = 701 K

T_2 = final temperature = 525 K

Substituting the provided values into this formula yields:

\log (\frac{K_2}{2.57M^{-1}s^{-1}})=\frac{1.5\times 10^5J/mol}{2.303\times 8.314J/mole.K}[\frac{1}{701K}-\frac{1}{525K}]

K_2=0.0606M^{-1}s^{-1}

Thus, the rate constant at 525 K is, 0.0606M^{-1}s^{-1}

8 0
2 months ago
Which of the following reactions would have the smallest value of K at 298 K? Which of the following reactions would have the sm
lorasvet [2795]
The reaction that exhibits the lowest K value is: A + B → 2 C; E°cell = -0.030 V. This can be rationalized by noting that the standard electrode potential of the cell is directly proportional to the reaction's equilibrium constant. A higher potential results in a larger K value, whereas a lower potential yields a smaller K value.
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2 months ago
Calculate the molarity of a 10.0% (by mass) aqueous solution of hydrochloric acid.
VMariaS [2998]

The question is incomplete,the complete question:

Determine the molality of a 10.0% (by weight) solution of hydrochloric acid in water:

a) 0.274 m

b) 2.74 m

c) 3.05 m

d) 4.33 m

e) the solution's density is necessary for calculations

Answer:

The molality for a 10.0% (by weight) hydrochloric acid solution is 3.05 mol/kg.

Explanation:

The solution is a 10.0% (by weight) hydrochloric acid mix.

This means there are 10 grams of HCl in 100 grams of the solution.

Amount of HCl = 10 g

Total mass of solution = 100 g

Total mass of solution = Mass of solute + Mass of solvent

Mass of solvent (water) = 100 g - 10 g = 90 g

Calculate moles of HCl = \frac{10 g}{36.5 g/mol}=0.2740 mol

Mass of water converted to kilograms = 0.090 kg

Molality = \frac{0.2740 mol}{0.090 kg}=3.05 mol/kg

<strongTherefore, the molality of a 10.0% (by weight) hydrochloric acid solution is 3.05 mol/kg.

6 0
2 months ago
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