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Mariana
2 months ago
14

A 600.0 mL sample of 0.20 MHF is titrated with 0.10 MNaOH. Determine the pH of the solution after the addition of 600.0 mL of Na

OH. The Ka of HF is 3.5×10?4.
Chemistry
1 answer:
KiRa [2.9K]2 months ago
5 0

Answer: pH=12.69

Explanation:

{\text{Moles of HF}=Molarity\times {\text{Volume of solution in liters}}

{\text{Moles of HF}=0.20M\times 0.6L=0.12 moles

HF\rightarrow H^++F^-

Initially 0.12               0       0

Equilibrium   0.12-x           x        x

K_a=\frac{[H^+][F^-]}{[HF]}

3.5\times 10^{-4}=\frac{x^2}{0.12-x}  

(overlooking the minor value of x compared to 0.12)

x=4.2\times 10^{-5}

0.06 moles of NaOH will neutralize 0.06 moles of H^+=4.2\times 10^{-5}

NaOH\rightarrow Na^++OH^-

{\text{Molesof NaOH}}=Molarity\times {\text{Volume of solution in liters}}

{\text{Moles of NaOH}}=0.10M\times 0.6L=0.06 moles

Now 4.2\times 10^{-5} moles of OH^- will be neutralized by 4.2\times 10^{-5} moles of H^+ and (0.06-4.2\times 10^{-5})=0.059 moles of OH^- will remain.

The molarity of OH^-=\frac{0.059moles}{1.2L}=0.049M

pOH=-\log[OH^-]=-\log[0.049]=1.31pH = 14 - pOH= 14 - 1.31 = 12.69

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