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1 month ago
13

The average bond energy (enthalpy) for a C=C double bond is 614 kJ/mol and that of a C−C single bond is 348 kJ/mol. Estimate the

energy needed to break only the π bond of the double bond of 2-butene. Express your answer numerically in joules per molecule.
Chemistry
1 answer:
eduard [2.7K]1 month ago
7 0
4.42x10⁻¹⁹ J/molecule Explanation: In a double bond, both sigma and pi bonds exist, while a single bond comprises only a sigma bond. Given that breaking both bonds requires 614 kJ/mol, while breaking just the sigma bond needs 348 kJ/mol, the energy specific to breaking the pi bond is calculated as E = 614 - 348 = 266 kJ/mol. Since 1 kJ equates to 1000 J, this correlates to 266,000 J/mol. With Avogadro's number (1 mol = 6.02x10²³ molecules), we calculate E = 266,000 J/mol * (1 mol/6.02x10²³ molecules) yields E = 4.42x10⁻¹⁹ J/molecule.
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