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Verdich
1 month ago
6

The reaction between nitrogen dioxide and carbon monoxide is NO2(g)+CO(g)→NO(g)+CO2(g)NO2(g)+CO(g)→NO(g)+CO2(g) The rate constan

t at 701 KK is measured as 2.57 M−1⋅s−1M−1⋅s−1 and that at 895 KK is measured as 567 M−1⋅s−1M−1⋅s−1. The activation energy is 1.5×102 1.5×102 kJ/molkJ/mol. Predict the rate constant at 525 KK .
Chemistry
1 answer:
eduard [2.7K]1 month ago
8 0

Response: The rate constant at 525 K is, 0.0606M^{-1}s^{-1}

Rationale:

Based on the Arrhenius equation,

K=A\times e^{\frac{-Ea}{RT}}

or,

\log (\frac{K_2}{K_1})=\frac{Ea}{2.303\times R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_1 = rate constant when 701K = 2.57M^{-1}s^{-1}

K_2 = rate constant when 525K =?

Ea = activation energy for the process = 1.5\times 10^2kJ/mol=1.5\times 10^5J/mol

R = gas constant = 8.314 J/mole.K

T_1 = initial temperature = 701 K

T_2 = final temperature = 525 K

Substituting the provided values into this formula yields:

\log (\frac{K_2}{2.57M^{-1}s^{-1}})=\frac{1.5\times 10^5J/mol}{2.303\times 8.314J/mole.K}[\frac{1}{701K}-\frac{1}{525K}]

K_2=0.0606M^{-1}s^{-1}

Thus, the rate constant at 525 K is, 0.0606M^{-1}s^{-1}

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What is the percentage by mass of solution formed by dissolving 36.0 grams of HCl in 98.0 grams of water?
eduard [2782]
Convert HCl and H2O to moles.

36.0 g of HCl = 0.987 moles HCl

98.0 g of H2O = 5.44 moles H2O

Based on the stoichiometric ratio for HCl,
there are 0.987 moles of H and 0.987 moles of Cl.

For H₂O, according to the stoichiometric ratio, you have 10.88 moles of H and 5.44 moles of O.

Combining them:
11.867 moles H
0.987 moles Cl
5.44 moles O

Revert the moles back to grams, then divide by the total mass and multiply by 100 for the percentage by mass.

11.867 moles H = 11.96 g H
0.987 moles Cl = 34.99 g Cl
5.44 moles O = 87.03 g O

11.96/(36.0+98.0)(100) = 8.93% for H
34.99/(36.0+98.0)(100) = 26.11% for Cl
87.03/(36.0+98.0)(100) = 64.96% for O.
4 0
1 month ago
Read 2 more answers
In KCI how are the valence electrons distributed
eduard [2782]

Answer:

Explanation:

In KCl, the two elements that combine to create KCl are potassium (K) and chlorine (Cl).

Potassium, as a Group 1 element, possesses one valence electron in its outermost shell which it readily donates during bonding. Every element aims to achieve a stable electron configuration, typically with 2 or 8 electrons in its outer shell. Potassium is characterized by its lower electronegativity and higher ionization energy, making it more likely to donate its electron than to accept one. On the other hand, chlorine belongs to Group 17 and has 7 electrons in its outer shell, requiring just one additional electron to complete its octet. Chlorine’s higher electronegativity and lower ionization energy facilitate its tendency to accept an electron rather than donate it.

The bond between potassium and chlorine that results in KCl is termed an electrovalent bond.

Reaction equation:

K + Cl → KCl

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1 month ago
Freon-11, CCl3F has been commonly used in air conditioners. It has a molar mass of 137.35 g/mol and its enthalpy of vaporization
alisha [2963]

Answer:

180.56 kilojoules of heat energy is extracted when 1.00 kg of freon-11 evaporates.

Explanation:

The molar mass of freon-11 is 137.35 g/mol

The enthalpy of vaporization for freon-11 is 24.8 kJ/mol at its normal boiling point of 24°C. Given that,\Delta H_{vap}=24.8 kJ/mol

Mass of freon-11 evaporated = 1.00 kg = 1000 g

Moles of freon-11 evaporated can be calculated as

\frac{1000 g}{137.35 g/mol}=7.2807 mol

The energy removed in the form of heat when 1.00 kg of freon-11 vaporizes is:

7.28067 mol\times \Delta H_{vap}=7.2807 mol\times 24.8 kJ/mol

=180.56 kJ

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13 days ago
A solution is prepared by adding 100 mL of 1.0 M HC2H3O2 (aq) to 100 mL of 1.0 M NaC2H3O2 (aq). The solution is stirred and its
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The correct equation is (C) H3O+(aq) + C2H3O2−(aq) -> HC2H3O2(aq) + H2O(l). A buffer system is composed of a weak acid and its corresponding salt, effectively stabilizing the pH levels within a solution. The buffer works by adjusting the concentrations of the conjugate acid and base, maintaining the pH constant.
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Alekssandra [3086]
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