Fe 3+ + SCN- --> FeSCN 2+
<span>.......Fe 3+.......SCN-.........FeSCN 2+ </span>
<span>I.......0.04..........0.001.............. </span>
<span>C........-x...............-x............. </span>
<span>E.....0.04-x.....0.001-x...........x </span>
<span>Keq = 203.4 = x / (0.04-x)(0.001-x) </span>
<span>203.4 = x / (x^2 - 0.041x + 4x10^-5) </span>
<span>203.4x^2 - 8.34x + 0.00094 = x </span>
<span>203.4x^2 - 9.34x + 0.00094 = 0 </span>
<span>x = -0.0001M or 0.0458M </span>
<span>therefore, according to the calculated Keq, all of the SCN- and Fe 3+ would be fully converted into FeSCN 2+</span>
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Response:
9.9 ml of 0.200M NH₄OH(aq)
Reasoning:
3NH₄OH(Iaq) + FeCl₃(aq) => NH₄Cl(aq) + Fe(OH)₃(s)
What volume in ml of 0.200M NH₄OH(aq) will fully react with 12ml of 0.550M FeCl₃(aq)?
1 x Molarity of NH₄OH x Volume of NH₄OH Solution(L) = 2 x Molarity of FeCl₃ x Volume of FeCl₃ Solution
1(0.200M)(Volume of NH₄OH Soln) = 3(0.550M)(0.012L)
=> Volume of NH₄OH Soln = 3(0.550M)(0.012L)/1(0.200M) = 0.0099 Liters = 9.9 milliliters
Answer: Reaction 2 is a spontaneous one.
Explanation:
According to our understanding:
= +ve, meaning the reaction is non-spontaneous
= -ve, indicating the reaction is spontaneous
= 0, stating that the reaction is at equilibrium
For a reaction to be classified as spontaneous, the Gibbs free energy must yield a negative value.
Reaction 1:
Glucose + Pi ⟶ glucose-6-phosphate + H₂O, ΔG = +13.8 kJ/mol
Reaction 2:
ATP + H₂O ⟶ ADP + Pi, ΔG = -30.5 kJ/mol
From this, we can conclude that ΔG being negative indicates that reaction 2 is indeed spontaneous.
