The accompanying illustration depicts the structure of dimethyl terephthalate. Explanation: Dimethyl terephthalate, whose chemical formula is C6H4 (COOCH3) 2, is a diester derived from terephthalic acid and methanol. It appears as a white solid. Another method of syntheses involves p-xylene and methanol, characterized by an oxidation process followed by esterification.
The negative sign indicates that heat is released.
When examining its electronic configuration, the last digit should be five, suggesting configurations like (2,5), (2,8,5), or (2,8,8,5), among others.
Thus, elements that end with the number 5 in their outer shell include N, P, As, Sb, Bi, Uup. Based on the choices presented, the probable answer is option 4) Phosphorus.
Bromocresol purple displays a color transition from yellow in its acidic form to purple in its basic form:
Bromocresol purple:
HIn + H₂O ⇄ In⁻ + H₃O⁺
yellow Purple
Upon completing the experiment, you should generate a graph resembling the one found in the practice guide. Refer to the accompanying image:
To identify the wavelength of peak absorbance for the pH < 4.0 solution, you should look at the curve plotted for pH 4. This curve exhibits a peak near 450 nm (inspect your graph closely). At this point, the solution appears yellow.
In order to determine the wavelength of maximum absorbance for the pH > 10.0 solution, focus on the line corresponding to pH 10. The apex of the curve should be around 590 nm, with the color at this wavelength being purple.
Regarding the last question: How do the observed colors of these solutions relate to the colors at their absorbance maxima? The colors we see are complementary to the colors at the wavelengths where absorption occurs. Specifically, 590 nm corresponds to red light. As red is absorbed, the color that is visible to us is its complement. The same principle applies to yellow, which is the complementary color of the absorbed wavelength.