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Natasha2012
2 months ago
9

When 1.34 g Zn(s) reacts with 60.0 mL of 0.750 M HCl(aq), 3.14 kJ of heat are produced. Determine the enthalpy change per mole o

f zinc reacting for the reaction:Zn(s) + 2HCl(aq) --> ZnCl₂(aq) + H₂(g)
Chemistry
1 answer:
Alekssandra [3K]2 months ago
5 0

Answer: The change in enthalpy for each mole of zinc involved in the reaction is 152.4 kJ/mol.

Explanation:

First, we need to determine the moles of Zn and HCl.

\text{Moles of }Zn=\frac{\text{Mass of }Zn}{\text{Molar mass of }Zn}

The molar mass of Zn is 65 g/mole

\text{Moles of }Zn=\frac{1.34g}{65g/mole}=0.0206mole

and,

\text{Moles of }HCl=\text{Concentration of }HCl\times \text{Volume of solution}=0.750M\times 0.0600=0.0450mole

Next, we must identify the limiting reagent and the excess reagent.

The chemical reaction given is:

Zn(s)+2HCl(aq)\rightarrow ZnCl_2(aq)+H_2(g)

According to the balanced reaction we find that

1 mole of Zn reacts with 2 moles of HCl

Thus, 0.0206 moles of Zn react with 0.0206\times 2=0.0412 moles of HCl

This leads us to determine that HCl is the excess reagent because the moles provided exceed the required moles, while Zn is limiting and restricts product formation.

Now to find the enthalpy change for each mole of zinc reacting in this reaction.

From the reaction we gather that,[ [TAG_59]]

0.0206 moles of Zn yield heat = 3.14 kJ

This implies that 1 mole of Zn generates heat = \frac{3.14kJ}{0.0206mol}=152.4kJ/mol

Hence, the enthalpy change per mole of zinc involved in this reaction amounts to 152.4 kJ/mol.

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Refer to the attached diagram related to this question.

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