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juin
2 months ago
5

Three blocks of the same mass are placed in front of you. Block A has a volume of

Chemistry
1 answer:
KiRa [2.9K]2 months ago
8 0

Given:

There are three blocks, labeled A, B, and C, each with identical mass.

The dimensions of block A, B, and C are 3.0 cm, 5.0 cm, and 10.0 cm, respectively.

To Find:

Determine which block exhibits the greater density.

Solution:

Density \rho is defined as:

\rho=\dfrac{M}{V}......1 )

Here, V represents volume.

The volume V for a cube can be calculated as:

V=a^3.......2 )

( In this context, a denotes the cube's side length )

From equation 1, we observe that if mass is constant, density is inversely proportional to volume.

Consequently, the cube with the smallest side will possess the highest density, which, in this scenario, is the block measuring 3 cm.

Thus, this concludes our solution.

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A sample of solid naphthalene is introduced into an evacuated flask. Use the data below to calculate the equilibrium vapor press
Tems11 [2777]

Answer: The vapor pressure of naphthalene within the flask remains at 2.906\times 10^{-4} atm.

Explanation:

The transformation from solid naphthalene to its gaseous form follows the equilibrium reaction:

C_{10}H_8(s)\rightleftharpoons C_{10}H_8(g)

  • The formula employed to determine the enthalpy change for the reaction is:  

\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f(product)]-\sum [n\times \Delta H^o_f(reactant)]

The formula for calculating the enthalpy change regarding the aforementioned reaction is:

\Delta H^o_{rxn}=(1\times \Delta H^o_f_{(C_{10}H_8(g))})-(1\times \Delta H^o_f_{(C_{10}H_8(s))})

The provided information includes:

\Delta H^o_f_{(C_{10}H_8(s))}=78.5kJ/mol\\\Delta H^o_f_{(C_{10}H_8(g))}=150.6kJ/mol

Substituting the values into the previous equation produces:

\Delta H^o_{rxn}=(1\times 150.6)-(1\times 78.5)=72.1kJ/mol

  • The formula utilized to compute Gibbs free energy change is of a reaction:

\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f(product)]-\sum [n\times \Delta G^o_f(reactant)]

The equation for the enthalpy change for the reaction is:

\Delta G^o_{rxn}=(1\times \Delta G^o_f_{(C_{10}H_8(g))})-(1\times \Delta G^o_f_{(C_{10}H_8(s))})

The given factors include:

\Delta G^o_f_{(C_{10}H_8(s))}=201.6kJ/mol\\\Delta G^o_f_{(C_{10}H_8(g))}=224.1kJ/mol

By inserting values from the above equation, we arrive at:

\Delta G^o_{rxn}=(1\times 224.1)-(1\times 201.6)=22.5kJ/mol

  • For the calculation of K_1 (at 25°C) regarding the provided value of Gibbs free energy, the following relationship is applied:

\Delta G^o=-RT\ln K_1

where,

\Delta G^o = Gibbs free energy = 22.5 kJ/mol = 22500 J/mol  (Conversion factor: 1kJ = 1000J)

R = Gas constant = 8.314J/K mol

T = temperature = 25^oC=[273+25]K=298K

K_1 = equilibrium constant at 25°C =?

Inserting values into the above equation yields:

22500J/mol=-(8.314J/Kmol)\times 298K\times \ln K_1\\\\K_1=1.14\times 10^{-4}

  • To determine the equilibrium constant at 35°C, we refer to the equation proposed by Arrhenius, which states:

\ln(\frac{K_2}{K_1})=\frac{\Delta H}{T}(\frac{1}{T_1}-\frac{1}{T_2})

where,

K_2 = Equilibrium constant at 35°C =?

K_1 = Equilibrium constant at 25°C = 1.14\times 10^{-4}

\Delta H = Enthalpy change of the reaction = 72.1 kJ/mol = 72100 J

R = Gas constant = 8.314J/K mol

T_1 = Initial temperature = 25^oC=[273+25]K=298K

T_2 = Final temperature = 35^oC=[273+35]K=308K

By plugging values into the equation above, we obtain:

\ln(\frac{K_2}{1.14\times 10^{-4}})=\frac{72100J/mol}{8.314J/K.mol}(\frac{1}{298}-\frac{1}{308})\\\\K_2=2.906\times 10^{-4}

  • In order to calculate the partial pressure of naphthalene at 35°C, we utilize the equation for K_p, which is:

K_p=\frac{p_{C_{10}H_8(g)}}{p_{C_{10}H_8(g)}}=p_{C_{10}H_8(g)

The partial pressure of the solid phase is considered to be 1 at equilibrium.

Therefore, the value for K_2 will equal K_p

p_{C_{10}H_8}=2.906\times 10^{-4}

Consequently, the partial pressure of naphthalene at 35°C is 2.906\times 10^{-4} atm.

3 0
2 months ago
The concentration of Si in an Fe-Si alloy is 0.25 wt%. What is the concentration in kilograms of Si per cubic meter of alloy?
KiRa [2933]

Answer: The mass of Si in kilograms is, 19.55kg/m^3

Explanation:

Given that the Si concentration in an Fe-Si alloy is 0.25 weight percent, this translates to:

Mass of Si = 0.25 g = 0.00025 kg

Mass of Fe = 100 - 0.25 = 99.75 g = 0.09975 kg

Density of Si = 2.32g/cm^3=2.32\times 10^6g/m^3

Density of Fe = 7.87g/cm^3=7.87\times 10^6g/m^3

Next, we need to find the quantity of Si in kilograms per cubic meter of alloy.

Si concentration in kilograms = \frac{\text{Weight of Si in 100 g of alloy}}{\text{Volume of 100 g of alloy}}

Si concentration in kilograms = \frac{\text{Weight of Si in 100 g of alloy}}{\frac{\text{Wight of Fe}}{\text{Density of Fe}}+\frac{\text{Wight of Si}}{\text{Density of Si}}}

By substituting all the provided values into this formula, we arrive at:

Si concentration in kilograms = \frac{0.00025kg}{\frac{99.75g}{7.87\times 10^6g/m^3}+\frac{0.25g}{2.23\times 10^6g/m^3}}

Si concentration in kilograms = 19.55kg/m^3

Hence, the mass of Si in kilograms is, 19.55kg/m^3

5 0
3 months ago
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