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ycow
8 days ago
6

An ice cube is placed on a kitchen counter. Which best describes heat flow in this situation

Chemistry
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PART A: Use the following glycolytic reaction to answer the question. If the concentration of DHAP is 0.125 M and the concentrat
alisha [2963]

Answer:

For A: The change in free energy for the reaction is -5339.76 J/mol

For B: Free energy change is expressed in kJ/mol

For C: The forward reaction favors progression, while the reverse reaction does not.

Explanation:

Regarding the specified chemical reaction:

DHAP\rightleftharpoons G_3P

  • For A:

The relationship between standard Gibbs free energy and equilibrium constant is as follows:

\Delta G^o=-RT\ln K_{eq}

The free energy change can be calculated using the following equation:

\Delta G=\Delta G^o+RT\ln Q

Or,

\Delta G=-RT^o\ln K_{eq}+RT\ln Q

where,

\Delta G = Change in free energy

R = Gas constant = 8.314J/K mol

T^o = standard temperature = 25^oC=[273+25]K=298K

T = temperature of the cell = 37^oC=[273+37]K=310K

K_[eq} = equilibrium constant = 5.4\times 10^{-2}

Q = reaction quotient = \frac{[G_3P]}{[DHAP]}

[G_3P] = 0.06 M

[DHAP] = 0.125 M

Substituting the values into the equation yields:

\Delta G=[-(8.314J/mol.K\times 298K\times \ln (5.4\times 10^{-2}))]+[(8.314J/mol.K\times 310K\times \ln (\frac{0.06}{0.125}))]\\\\\Delta G=-[-7231.46]+[-1891.7]=-5339.76J/mol

Thus, the change in free energy for the reaction is -5339.76 J/mol

  • For B:

To convert the free energy change to kilojoules, we apply the conversion factor:

1 kJ = 1000 J

So, -5339.76J/mol\times \frac{1kJ}{1000J}=-5.34kJ/mol

Consequently, the free energy change's units are kJ/mol

  • For C:

For spontaneity in the reaction, the Gibbs free energy must be negative. However, the calculations indicate a positive Gibbs free energy, leading to the conclusion that the reaction is not spontaneous.

The free energy change of the reaction is negative.

Consequently, the forward reaction is favored and the reverse reaction is not favored.

8 0
2 months ago
32.7 grams of water vapor takes up how many liters at standard temperature and pressure (273 K and 100 kPa)?
alisha [2963]
At standard temperature and pressure, it is established that 1 mole of gas has a volume of 22.4 liters.

According to the periodic table:
the molar mass of oxygen is 16 g
and the molar mass of hydrogen is 1 g
Hence, the molar mass of water vapor is calculated as 2(1) + 16 = 18 g

Thus, 18 g of water occupies 22.4 liters, therefore:
the volume for 32.7 g is (32.7 x 22.4) / 18 = 40.6933 liters

5 0
2 months ago
In a chemical reaction, 300 grams of reactant A are combined with 100 grams of reactant B. Both A and
KiRa [2933]
I expect the product's mass to be 400 grams. This belief stems from the law of conservation of mass, which states that mass can neither be created nor destroyed. In a sealed system, the mass of the reactants equals the mass of the products. Therefore, since the total mass of the reactants is 400 grams, the resulting mass of the products must also be 400 grams

OR

200

8 0
2 months ago
How many 2º alkyl bromides, neglecting stereoisomers, exist with the formula c6h13br?
Anarel [2989]

A secondary alkyl halide would be characterized by having a carbon atom connected to two other carbon atoms, with bromine attached to that carbon.


Therefore, bromo-hexane qualifies as a 2-degree or secondary alkyl halide


5 0
1 month ago
What is the mass in grams of KBr in 0.400 L of a 0.350 M solution???
Anarel [2989]
The mass of KBr required is 16.7 g. This concludes from a volume of 0.400 L and a concentration of 0.350 M. Utilizing the molarity formula, moles are calculated as 0.14, leading to a molecular weight calculation of 119 g/mol, thus resulting in a mass of 16.7 g of KBr.
8 0
1 month ago
Read 2 more answers
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