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Sidana
3 days ago
7

Given these reactions, where X represents a generic metal or metalloid 1) H2(g)+12O2(g)⟶H2O(g)ΔH1=−241.8 kJ 1) H2(g)+12O2(g)⟶H2O

(g)ΔH1=−241.8 kJ 2) X(s)+2Cl2(g)⟶XCl4(s)ΔH2=+356.9 kJ 2) X(s)+2Cl2(g)⟶XCl4(s)ΔH2=+356.9 kJ 3) 12H2(g)+12Cl2(g)⟶HCl(g)ΔH3=−92.3 kJ 3) 12H2(g)+12Cl2(g)⟶HCl(g)ΔH3=−92.3 kJ 4) X(s)+O2(g)⟶XO2(s)ΔH4=−639.1 kJ 4) X(s)+O2(g)⟶XO2(s)ΔH4=−639.1 kJ 5) H2O(g)⟶H2O(l)ΔH5=−44.0 kJ 5) H2O(g)⟶H2O(l)ΔH5=−44.0 kJ what is the enthalpy, ΔH,ΔH, for this reaction? XCl4(s)+2H2O(l)⟶XO2(s)+4HCl(g)
Chemistry
1 answer:
Tems11 [839]3 days ago
5 0

Response:

ΔH = -793.6 kJ

Reasoning:

The ΔH for this particular reaction can be calculated through Hess's law, which allows one to combine the ΔH values of the half-reactions to find the overall ΔH:

The half-reactions are as follows:

1) H₂(g) + ¹/₂O₂(g) ⟶ H₂O(g) ΔH₁ = −241.8 kJ

2) X(s) + 2Cl₂(g) ⟶ XCl₄(s) ΔH₂ = +356.9 kJ

3) ¹/₂H₂(g) + ¹/₂Cl₂(g) ⟶ HCl(g) ΔH₃ = −92.3 kJ

4) X(s) + O₂(g) ⟶ XO₂(s) ΔH₄ = −639.1 kJ

5) H₂O(g) ⟶ H₂O(l) ΔH₅ = −44.0 kJ

The calculation involves summing (4) + 4×(3) - (2) - 2×(1) - 2×(5):

(4) X(s) + O₂(g) ⟶ XO₂(s) ΔH = −639.1 kJ

+4×(3) 2H₂(g) + 2Cl₂(g) ⟶ 4HCl(g) ΔH = −369.2 kJ

-(2) XCl₄(s) ⟶ X(s) + 2Cl₂(g) ΔH = -356.9 kJ

-2×(1) 2H₂O(g) ⟶ 2H₂(g) + O₂(g) ΔH = +483.6 kJ

-2×(5) 2H₂O(l) ⟶ 2H₂O(g) ΔH = +88.0 kJ

= XCl₄(s) + 2H₂O(l) ⟶ XO₂(s) + 4HCl(g)

<pThus, ΔH is:

ΔH = -639.1 kJ -369.2 kJ -356.9 kJ +483.6 kJ +88.0 kJ

ΔH = -793.6 kJ

I trust this clarifies things!

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1 day ago
You want to prepare a solution with a concentration of 200.0μM from a stock solution with a concentration of 500.0mM. At your di
lorasvet [946]

Answer:

1) This dilution plan will yield a 200μM solution.

2) This dilution plan will not yield a 200μM solution.

3) This dilution plan will not yield a 200μM solution.

4) This dilution plan will yield a 200μM solution.

5) This dilution plan will yield a 200μM solution.

Explanation:

Convert the initial molarity into molar form as shown.

500mM = 500mM \times (\frac{1M}{1000M})= 0.5M

Let's examine the following serial dilution processes.

1)

Dilute 5.00 mL of the stock solution to 500 mL. Then take 10.00 mL of this new solution and dilute it further to 250 mL.

Concentration of 500 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{500 mL}= 5 \times 10^{-3}M

10 mL of this solution is further diluted to 250 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(5 \times 10^{-3}M)(10.0mL)}{250 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

2)

Dilute 5.00 mL of the stock solution to 100 mL. Then take 10.00 mL of this new solution and dilute to 1000 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{100 mL}= 2.5 \times 10^{-2}M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(2.5 \times 10^{-2}M)(10.0mL)}{1000 mL}= 2.5 \times 10^{-4}M

Convert μM:

2.5 \times 10^{-4}M = (2.5 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 250 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

3)

Dilute 10.00 mL of the stock solution to 100 mL, followed by diluting 5 mL of that new solution to 100 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{100 mL}= 0.05M

5 mL of this solution is diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.05M)(5mL)}{1000 mL}= 0.25 \times 10^{-4}M

Convert μM:

0.25 \times 10^{-4}M = (0.25 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 25 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

4)

Dilute 5 mL of the stock solution to 250 mL. Then take 10 mL of this new solution and further dilute it to 500 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5mL)}{250 mL}= 0.01M

10 mL of this solution is further diluted to 500 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.01M)(10mL)}{500 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

5)

Dilute 10 mL of the stock solution to 250 mL. Then take another 10 mL of this new solution and dilute it to 1000 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{250 mL}= 0.02M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.02M)(10mL)}{1000 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

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9 days ago
The volume of a gas at 6.0 atm is 2.5 L. What is the volume of the gas at 7.5 atm at the same temperature?
castortr0y [918]

Greetings!

The result is:

The new volume is: 2L

Rationale:

Because the temperature remains constant, we can apply Boyle's Law to solve this issue.

Boyle's Law stipulates that:

P_{1}V_{1}=P_{2}V_{2}

Where,

P is the gas's pressure.

V is the gas's volume.

According to the information provided:

V_{1}=2.5L\\P_{1}=6.0atm\\P_{2}=7.5atm

Let's put the values into the equation:

2.5L*6.0atm=7.5atm*V_{2}

2.5L*6.0atm=7.5atm*V_{2}\\\\V_{2}=\frac{2.5L*6.0atm}{7.5atm}=\frac{15L.atm}{7.5atm}=2L

Consequently, the new volume is: 2L

Wishing you a lovely day!

7 0
2 days ago
(a) The original value of the reaction quotient, Qc, for the reaction of H2(g) and I2(g) to form HI(g) (before any reactions tak
KiRa [965]

Response:

Here's my calculation

Clarification:

Assume the starting concentrations of H₂ and I₂ are 0.030 and 0.015 mol·L⁻¹, respectively.

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2. Calculate the concentration of HI

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3. Plot the initial values

The graph below visualizes the initial concentrations as plotted on the vertical axis.

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