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MaRussiya
1 month ago
10

Addition of an excess of lead (II) nitrate to a 50.0mL solution of magnesium chloride caused a formation of 7.35g of lead (II) c

hloride precipitate. What was the molar concentration of chloride ions in the solution (in mol/L)?
Chemistry
1 answer:
KiRa [2.9K]1 month ago
3 0

Answer:

[Cl⁻] = 0.016M

Explanation:

To begin, we analyze the reaction:

Pb(NO₃)₂ (aq) + MgCl₂ (aq) → PbCl₂ (s) ↓  +  Mg(NO₃)₂(aq)

This indicates a solubility equilibrium, resulting in the formation of lead(II) chloride precipitate. The salt can dissociate as follows:

           PbCl₂(s)  ⇄  Pb²⁺ (aq)  +  2Cl⁻ (aq)     Kps

Initial        x

React       s

Eq          x - s              s                  2s

Given that this is an equilibrium scenario, the Kps serves as the constant (Solubility product):

Kps = s. (2s)²

Kps = 4s³ = 1.7ₓ10⁻⁵

4s³ = 1.7ₓ10⁻⁵

s =  ∛(1.7ₓ10⁻⁵. 1/4)

s = 0.016 M

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eduard [2782]
Based on the equation:

ΔG = ΔH - TΔS = 0

It follows that ΔS = ΔH/T

So, ΔS = n*ΔHVap / Tvap

- where n represents the number of moles calculated as mass/molar mass

For a mass of 24.1 g

and a molar mass of 187.3764 g/mol

substituting gives:

∴ n = 24.1 / 187.3764g/mol

      = 0.129 moles

The molar enthalpy of vaporization, ΔHvap, is 27.49 kJ/mol

The temperature in Kelvin, Tvap = 47.6 + 273 = 320.6 K

After substitution, we compute ΔS, the change in entropy:

∴ΔS = 0.129 mol * 27490 J/mol / 320.6 K

      = 11 J/K
7 0
1 month ago
A saturated solution of potassium iodide contains, in each 100 mL, 100 g of potassium iodide. The solubility of potassium iodide
KiRa [2933]

Answer:

The specific gravity of the saturated solution is 2

Explanation:

Specific gravity represents the ratio of the density of a solution, in this case, a saturated potassium iodide (KI) solution, to the density of water. Assuming the density of water is 1:

Specific gravity  = Density

Density itself is defined as the mass divided by volume.

In 100mL of water, the mass of dissolve-able KI is:

100mL * (1g KI / 0.7mL) = 143g of KI

This indicates that all 100g of KI dissolves (Mass solute)

With 100mL of water corresponding to a mass of 100g (Mass solvent)

The overall mass of the solution computes to 100g + 100g = 200g

In a volume of 100mL, the solution's density is:

200g / 100mL = 2g/mL.

Specific gravity is a dimensionless quantity, thus the specific gravity of the saturated solution is 2

5 0
15 days ago
Albus Dumbledore provides his students with a sample of 19.3 g of sodium sulfate. How many oxygen atoms are in this sample
eduard [2782]
The amount of oxygen atoms present is approximately 3.27·10²³. To determine this figure, we must first assess the sodium sulfate sample. The chemical formula for it is Na₂SO₄, which possesses a molar mass of roughly 142.05 g/mol. We can then use stoichiometry to convert the mass of Na₂SO₄ into moles. By knowing the moles of Na₂SO₄, we will subsequently convert this to moles of oxygen utilizing the mole ratio and finally apply Avogadro's number to convert to atoms of oxygen. Thus, with the calculations completed, the resulting quantity of oxygen atoms is about 3.27·10²³.
3 0
17 days ago
How many grams of AlF3 are in 2.64 moles of AlF3?
Anarel [2989]
To determine the mass of AlF3 in 2.64 moles of AlF3, we use the formula: mass = moles x molar mass, which results in 221.76 grams of AlF3.
3 0
1 month ago
What is [h3o ] in a solution of 0.25 m ch3co2h and 0.030 m nach3co2?
Anarel [2989]

Hello!

To find [H₃O⁺], we will employ the Henderson-Hasselbalch equation, as this involves an acid and its conjugate base:

pH=pKa+log( \frac{[A^{-}] }{[HA]} )

pH=4,76+log( \frac{0,030M}{0,25M} ) \\ \\ pH=3,84

Next, we derive [H₃O⁺] using the definition of pH:

pH=-log[H_3O^{+}]

[H_3O^{+}] = 10^{-pH} =10^{-3,84}=0,00014 M

Hence, the concentration of [H₃O⁺] comes out to be 0.00014 M

Wishing you a good day!

4 0
1 month ago
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