Fe 3+ + SCN- --> FeSCN 2+
<span>.......Fe 3+.......SCN-.........FeSCN 2+ </span>
<span>I.......0.04..........0.001.............. </span>
<span>C........-x...............-x............. </span>
<span>E.....0.04-x.....0.001-x...........x </span>
<span>Keq = 203.4 = x / (0.04-x)(0.001-x) </span>
<span>203.4 = x / (x^2 - 0.041x + 4x10^-5) </span>
<span>203.4x^2 - 8.34x + 0.00094 = x </span>
<span>203.4x^2 - 9.34x + 0.00094 = 0 </span>
<span>x = -0.0001M or 0.0458M </span>
<span>therefore, according to the calculated Keq, all of the SCN- and Fe 3+ would be fully converted into FeSCN 2+</span>
The visual representation is displayed in the following image.
For calculations, consider 100 grams of the compound:
ω(Cl) = 85.5% ÷ 100%.
ω(Cl) = 0.855; signifying the mass percentage of chlorine in the compound.
m(Cl) = 0.855 · 100 g.
m(Cl) = 85.5 g; this represents the mass of chlorine.
m(C) = 100 g - 85.5 g.
m(C) = 14.5 g; indicating the mass of carbon.
n(Cl) = m(Cl) ÷ M(Cl).
n(Cl) = 85.5 g ÷ 35.45 g/mol.
n(Cl) = 2.41 mol; this is the quantity of chlorine.
n(C) = 14.5 g ÷ 12 g/mol.
n(C) = 1.21 mol; this is the quantity of carbon.
n(Cl): n(C) = 2.41 mol: 1.21 mol = 2: 1.
The compound in question is identified as dichlorocarbene CCl₂.
A total of 0.0222 moles of NaOH are necessary to react with NH4F. \nBased on the reaction NH4F + NaOH --> NaF + NH3 + H2O, we start with: \nMass of NH4F = 0.821 g, NaOH concentration = 1 M, volume of NaOH = 25 mL. \nTo find moles: moles of NaOH = (CV)/1000. Thus, moles of NaOH = (1 * 25)/1000 = 0.025 moles of NaOH used. \nThe molar mass of NH4F is 37 g/mol, making moles of NH4F = 0.821 / 37 = 0.0222 moles. \nThis shows that NaOH is in excess, with 0.025 - 0.0222 = 0.0028 moles of NaOH remaining. Hence, 0.0222 moles of NaOH are needed to react with NH4F.
<span>Some solutions demonstrate colligative properties, which rely on the quantity of solute in a solvent. To find the elevation in boiling point, we use the formula:
</span><span>ΔT(boiling point) =
(Kb)mi
where Kb represents a constant, m is the solution's molality, and i is the van't Hoff factor.
From the provided information, we can easily determine i as follows:
</span>ΔT(boiling point) = (Kb)mi
103.45 - 100 = (0.512)3.90i
i = 1.73 <-------van't Hoff factor
Answer:
Central metal oxidation state: +2
Coordination number: 6
Overall charge: -2
Explanation:
For the ion complex:
Na₂[Cr(NH₃)₂(NCS)₄]
The central metal is chromium, with NH₃ and NCS as the ligands.
NH₃ acts as a neutral ligand, while NCS carries a negative charge.
The entire complex has a charge of:
2Na⁺ + [Cr(NH₃)₂(NCS)₄]⁻² → -2
Since each NCS contributes -1 and there are four NCS, the Cr must possess an oxidation state of +2 to achieve an overall charge of -2.
With 2 NH₃ and 4 NCS attached, the coordination number sums to 2+4 = 6
I trust this clarifies the matter!
