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Sergeeva-Olga
14 days ago
6

What is the activation energy (in kJ/mol) of a reaction whose rate constant increases by a factor of 89 upon increasing the temp

erature from 307 K to 343 K? R = 8.314 J/(mol • K). Only enter the numerical value as an integer in the answer box below. Do NOT type in the unit (kJ/mol).
Chemistry
1 answer:
lorasvet [2.5K]14 days ago
3 0
15.9 KJ/mol Explanation: Given data: Temperature = T1 = 307 K, Temperature = T2 = 343 K, Gas constant R = 8.314 J/(mol • K), rate constant = k2/K1 = 89. To determine: Activation energy (in kJ/mol) = Ea =? Formula: The Arrhenius equation establishes the relationship between temperature and reaction rates. Here, in this equation, k = the rate constant, Ea = the activation energy, R = the Universal Gas Constant, T = the temperature. Solution: ln 89 = Ea / 8.314 J/mol.K * (0.0325 - 0.00291). then ln 89 = Ea / 8.314 J/mol.K * (2.95 x 10^2). Resulting in 4.488 = Ea / 8.314 J/mol.K * (2.95 x 10^2). Therefore, Ea = 4.488 * (2.95 x 10^2) / 8.314 J/mol.K which simplifies to Ea = 0.1324 / 8.314. Thus, Ea = 0.0159 and finally, Ea = 1.59 x 10^2 J/mol or 15.9 KJ/mol.
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A 19.3-g mixture of oxygen and argon is found to occupy a volume of 16.2 l when measured at 675.9 mmhg and 43.4oc. what is the p
KiRa [2726]
<span>The partial pressure of oxygen is 438.0 mmHg. The ideal gas equation is expressed as PV = nRT where P represents pressure, V denotes volume, n is the number of moles, R is the ideal gas constant (8.3144598 (L*kPa)/(K*mol)), and T signifies absolute temperature. To convert from Celsius to Kelvin, we have 43.4 + 273.15 = 316.55 K. For the pressure conversion from mmHg to kPa: 675.9 mmHg * 0.133322387415 = 90.11260165 kPa. When solving for n using the ideal gas equation, we derive n = PV / (RT) which provides n = 90.11260165 kPa * 16.2 L / (8.3144598 (L*kPa)/(K*mol) * 316.55 K)= 1459.824147 L*kPa / 2631.94225 (L*kPa)/(mol), resulting in n = 0.554656603 mol. Thus, we have 0.554656603 moles of gas particles. Next, we determine the contribution from oxygen. The atomic weight of oxygen is 15.999 g/mol, while argon is 39.948 g/mol, and the molar mass of O2 is 31.998 g/mol. We establish the relationships where M is the number of moles of O2, and 0.554656603 - M gives the number of moles of Ar. Setting up the equation: M * 31.998 + (0.554656603 - M) * 39.948 = 19.3, we solve for M resulting in 0.359424148 moles of oxygen out of 0.554656603 total moles. This leads to oxygen providing 0.359424148 / 0.554656603 = 0.648012024 or 64.8012024% of the total pressure of 675.9 mmHg. The partial pressure therefore calculates to 675.9 * 0.648012024 = 437.9913271 mmHg, rounded to 438.0 mmHg</span>
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19 days ago
Which statement is correct? Salts are formed by the reaction of bases with water. Most salts are ionic and are soluble in water.
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3 0
1 month ago
Read 2 more answers
A 20.0–milliliter sample of 0.200–molar K2CO3 so­lution is added to 30.0 milliliters of 0.400–mo­lar Ba(NO3)2 solution. Barium c
KiRa [2726]

Respuesta:

0.16 M

Explicación:

Teniendo en cuenta:

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

O sea,

Moles =Molarity \times {Volume\ of\ the\ solution}

Dado que:

Para K_2CO_3 :

Molaridad = 0.200 M

Volumen = 20.0 mL

Convierte mL a L:

1 mL = 10⁻³ L

Entonces, volumen = 20.0×10⁻³ L

Los moles de K_2CO_3 son:

Moles=0.200 \times {20.0\times 10^{-3}}\ moles

Moles de K_2CO_3 = 0.004 moles

Para Ba(NO_3)_2 :

Molaridad = 0.400 M

Volumen = 30.0 mL

Convertimos mL a L:

1 mL = 10⁻³ L

Volumen = 30.0×10⁻³ L

Entonces, los moles de Ba(NO_3)_2 son:

Moles=0.400 \times {30.0\times 10^{-3}}\ moles

Moles de Ba(NO_3)_2 = 0.012 moles

Según la reacción:

Ba(NO_3)_2 + K_2CO_3\rightarrow BaCO_3 + 2KNO_3

1 mol de Ba(NO_3)_2 reacciona con 1 mol de K_2CO_3

Por lo tanto,

0.012 mol de Ba(NO_3)_2 reacciona con 0.012 mol de K_2CO_3

Moles disponibles de K_2CO_3 = 0.004 mol

El reactivo limitante es el que está en menor cantidad, entonces K_2CO_3 es el limitante (0.004 < 0.012).

La formación del producto depende del reactivo limitante, así que,

1 mol de K_2CO_3 reacciona con 1 mol de Ba(NO_3)_2 y produce 1 mol de BaCO_3

0.004 mol de K_2CO_3 reacciona con 0.004 mol de Ba(NO_3)_2 y genera 0.004 mol de BaCO_3

Los moles restantes de Ba(NO_3)_2 son: 0.012 - 0.004 = 0.008 mol

El volumen total es 20 + 30 mL = 50 mL = 0.050 L

Por lo que la concentración del ion bario, Ba^{2+}, después de la reacción es:

Molarity=\frac{0.008}{0.050}\ M = 0.16\ M

3 0
1 month ago
Given two half reactions as follows: A2+ → 2 A2+ + 3 e− 4 e− + B → B4− What would you multiply each half-reaction by, to cancel
Tems11 [2403]
To achieve the cancellation of electrons, the oxidation half-reaction needs to be multiplied by 4 while the reduction half-reaction must be multiplied by 3. Explanation: The oxidation reaction accounts for the loss of electrons, increasing the oxidation state, while the reduction implies gaining electrons, leading to a decrease in oxidation state. The respective half-reactions illustrate this, confirming that multiplying the oxidation by 4 and the reduction by 3 achieves the desired effect.
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14 days ago
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