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Lina20
2 months ago
10

You prepared the buffer by adding about 0.2 g of each of the weak acid and its conjugate base to 25.0 mL of water. The goal was

to produce a buffer near its point of maximum buffer capacity where [WA] = [CB]. An alternative approach could have been to dissolve about 0.4 g of the weak acid in water, and then add enough NaOH to convert half the weak acid into its conjugate base. How many mL of 0.10 M NaOH would have been needed to achieve this result?
Chemistry
1 answer:
eduard [2.7K]2 months ago
3 0

Answer:

To achieve the desired outcome, 8.55 mL of NaOH is necessary.

Explanation:

Considering that:

the weak acid has a mass of 0.4 g

and a molecular weight of 234 g/mol

so, the number of moles of the weak acid is calculated as 0.4 g/234 g/mol = 0.00171 mole

To convert half of the weak acid (WA) to conjugate base (CB), we must add NaOH.

Thus, [WA]=[CB] 0.00171/2 = 8.55×10⁻⁴ mole of NaOH required

Further, knowing that the concentration of NaOH is 0.10 M

the volume needed to achieve this result can be calculated as follows:

8.55*10^{-4}*\frac{1 \ L}{0.1 \ M}

= 8.55*10^{-4}*\frac{1 000}{0.1 }

= 8.55 mL of NaOH is necessary

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