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stellarik
11 days ago
8

18. How many milliliters of water at 23 °C with a density of 1.00 g/mL must be mixed with 180 mL (about 6 oz) of coffee at 95 °C

so that the resulting combination will have a temperature of 60 °C? Assume that coffee and water have the same density and the same specific heat.
Chemistry
1 answer:
Anarel [2.9K]11 days ago
3 0

Answer:

The amount of water needed to mix with the solution is 170.27 mL

Explanation:

Provided details:

Water temperature (T_{1}) = 23^{o}C

density of water (ρ) = 1.00 g/mL

Coffee temperature  (T_{1}) = 95^{o}C

Coffee volume (V_{2}) = 180 mL

Mixed Temperature (T_{mix}) = 60^{o}C

To calculate the heat, we apply the formula:

Q = m x c x ΔT

where

m = mass (g)

c = specific heat (J/g^{o}C)

ΔT = temperature change (^{o}C)

In this mixed solution, the water's heat (Q_{1}) must equal the coffee's heat (Q_{2}). Thus,

Q_{1} = Q_{2}

m_{1} x c_{1} x ΔT_{1} = m_{2} x c_{2} x ΔT_{2}

where

m_{1} is the water’s mass

is the coffee’s massm_{2}

refers to the specific heat of water

c_{1} and

is the specific heat of coffeec_{2}

Assuming the specific heats of both coffee and water are identical, therefore,

c_{1} = c_{2}, can be canceled in the equation.

Thus,.

m_{1} x ΔT_{1} = m_{2} x ΔT_{2}

We know that

ρ = \frac{m}{V}

m = ρ x V, substitute this in the equation:

ρ_{1} x V_{1} x ΔT_{1} = ρ_{2} x V_{2} x ΔT_{2}

V_{1}is the volume of water

Since coffee and water share the same density, hence, we can eliminate the formula

V_{1} x ΔT_{1} = V_{2} x ΔT_{2}

Thus, V_{1} = (V_{2} x ΔT_{2}) / ΔT_{1}V_{1} = V_{2} x (\frac{(T_{2} - T_{mix}) }{(T_{mix} - T_{1})}

V_{1} = 180 mL x \frac{(95-60)^{o}C}{(60-23)^{o}C}

V_{1} = 180 mL x \frac{(35)^{o}C}{(37)^{o}C}

V_{1} = 170.27 mL

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Clarification:

The pertinent information is outlined as follows.

m = 10.0 kg = 10,000 g (since 1 kg = 1000 g)

Starting temperature of block 1, T_{1} = 100^{o}C = (100 + 273) K = 373 K

Starting temperature of block 2, T_{2} = 0^{o}C = (0 + 273) K = 273 K

Therefore, the heat lost by block 1 equals the heat received by block 2

mC \Delta T = mC \times \Delta T

10000 g \times 0.385 \times (T_{f} - 100)^{o}C = 10000 g \times 0.385 \times (0 - T_{f})^{o}C

T_{f} - 100^{o}C = 0^{o}C - T_{f}

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T_{f} = 50^{o}C

It's important to convert the temperature into Kelvin as (50 + 273) K = 323 K.

Additionally, the relationship between enthalpy and temperature change is as follows.

\Delta H = mC \Delta T

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\Delta S_{1} = mC ln \frac{T_{f}}{T_{i}}

= 10000 g \times 0.385 J/K g \times ln \frac{323}{373}

= 10000 g \times 0.385 J/K g \times -0.143

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Now, the entropy change for block 2 is as follows.

   \Delta S_{2} = mC ln \frac{T_{f}}{T_{i}}

           = 10000 g \times 0.385 J/K g \times ln \frac{323}{273}

           = 10000 g \times 0.385 J/K g \times 0.168

           = 647.49 J/K

Thus, the total entropy is the sum of the entropy changes of both blocks.

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In conclusion, for this reaction, the outcome is 1243.5 kJ and \Delta S_{total} is 93.37 J/K.

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5060 has three significant figures: Below is the clarification

Explanation:

Significant figures

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These include all digits except: leading zeros.

Guidelines for determining significant figures

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2. Zeros located between two non-zero digits are significant; for example, 202.1201 contains seven significant figures.

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4. Zeros following the significant figures are significant.

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Explanation:


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