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Orlov
1 month ago
15

The final overall chemical equation is Upper Ca upper O (s) plus upper C upper O subscript 2 (g) right arrow upper C a upper C u

pper O subscript 3 (s).. When the enthalpy of this overall chemical equation is calculated, the enthalpy of the second intermediate equation is halved and has its sign changed. is halved. has its sign changed. is unchanged.
Chemistry
1 answer:
lions [2.9K]1 month ago
7 0

Answer:

The enthalpy of the second intermediate equation is altered by halving its value and changing the sign.

Explanation:

Let's examine both the first and second intermediate reactions alongside the overall equation concerning the examined process;

First reaction;

Ca (s) + CO₂ (g) + ½O₂ (g) → CaCO₃ (s) ΔH₁ = -812.8 kJ

Second reaction;

2Ca (s) + O₂ (g) → 2CaO (s) ΔH₂ = -1269 kJ

Thus, the overall reaction becomes;

CaO (s) + CO₂ (g) → CaCO₃ (s) ΔH =?

According to Hess's law, which states that the total heat change in a reaction is equal to the sum of the heat changes for each step, we cannot simply sum the enthalpies for this overall reaction. Instead, we obtain the overall enthalpy by halving the second intermediate reaction's enthalpy and changing its sign before adding, as illustrated below;

Enthalpy of Intermediate reaction 1 + ½(-Enthalpy of Intermediate reaction 2) = Enthalpy of Overall reaction

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