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kow
1 month ago
11

In a reaction, gaseous reactants form a liquid product. The heat absorbed by the surroundings is 1.1 MJ, and the work done on th

e system is 13.2 kcal. Calculate ΔE (in kJ). Be sure to include the correct sign (+/-). Enter to 0 decimal places.
Chemistry
1 answer:
alisha [2.9K]1 month ago
4 0

Answer: \Delta E is 1155 kJ

Explanation:

The first law of thermodynamics states:

\Delta E=q+w

\Delta E=Change in internal energy

q represents the heat exchanged, either absorbed or released

w pertains to the work done by or on the system

w = work performed on the system=-P\Delta V  {Since work is done on the system, it is positive because the final volume is less than the initial volume}

w =13.2kcal=55.2kJ   (1kcal=4.184 kJ)

q amounts to +1.1 MJ = 1100 kJ  (1MJ=1000kJ)   {The system absorbs heat, making this value positive}

\Delta E=1100kJ+(55.2)kJ=1155kJ

Consequently, \Delta E is 1155 kJ

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You want to prepare a solution with a concentration of 200.0μM from a stock solution with a concentration of 500.0mM. At your di
lorasvet [2795]

Answer:

1) This dilution plan will yield a 200μM solution.

2) This dilution plan will not yield a 200μM solution.

3) This dilution plan will not yield a 200μM solution.

4) This dilution plan will yield a 200μM solution.

5) This dilution plan will yield a 200μM solution.

Explanation:

Convert the initial molarity into molar form as shown.

500mM = 500mM \times (\frac{1M}{1000M})= 0.5M

Let's examine the following serial dilution processes.

1)

Dilute 5.00 mL of the stock solution to 500 mL. Then take 10.00 mL of this new solution and dilute it further to 250 mL.

Concentration of 500 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{500 mL}= 5 \times 10^{-3}M

10 mL of this solution is further diluted to 250 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(5 \times 10^{-3}M)(10.0mL)}{250 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

2)

Dilute 5.00 mL of the stock solution to 100 mL. Then take 10.00 mL of this new solution and dilute to 1000 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{100 mL}= 2.5 \times 10^{-2}M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(2.5 \times 10^{-2}M)(10.0mL)}{1000 mL}= 2.5 \times 10^{-4}M

Convert μM:

2.5 \times 10^{-4}M = (2.5 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 250 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

3)

Dilute 10.00 mL of the stock solution to 100 mL, followed by diluting 5 mL of that new solution to 100 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{100 mL}= 0.05M

5 mL of this solution is diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.05M)(5mL)}{1000 mL}= 0.25 \times 10^{-4}M

Convert μM:

0.25 \times 10^{-4}M = (0.25 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 25 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

4)

Dilute 5 mL of the stock solution to 250 mL. Then take 10 mL of this new solution and further dilute it to 500 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5mL)}{250 mL}= 0.01M

10 mL of this solution is further diluted to 500 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.01M)(10mL)}{500 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

5)

Dilute 10 mL of the stock solution to 250 mL. Then take another 10 mL of this new solution and dilute it to 1000 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{250 mL}= 0.02M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.02M)(10mL)}{1000 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

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1 month ago
For each reaction, identify the element that gets reduced and the element that gets oxidized. 2AgCl+Zn⟶2Ag+ZnCl2 Identify the el
KiRa [2933]

Answer:

Explanation:

The oxidation state corresponds to the charge of each atomic ion. An increase indicates oxidation of the element while a decrease reflects reduction of the element.

2AgCl+Zn⟶2Ag+ZnCl2

Zinc undergoes oxidation, while Ag experiences reduction.

Ag⁺ changes to Ag (oxidation state decreases), thus Ag is reduced.

Zn alters to Zn⁺² (oxidation state increases), hence Zn is oxidized.

4NH₃+3O₂⟶2N₂+6H₂O

The oxidation state of nitrogen in ammonia is -3

whereas it is zero in elemental nitrogen.

An increase in the oxidation state indicates nitrogen is oxidized.

The oxidation state of oxygen is zero when in molecular oxygen and -2 when in water. Therefore, the oxidation state decreases, indicating oxidation is reduced.

Fe₂O₃+2Al⟶Al₂O₃+2Fe

The oxidation state of Fe in Fe₂O₃ is +3, switching to zero in Fe, so iron is reduced.

Aluminum's oxidation state is zero in Al, rising to +3 in Al₂O₃, indicating it is oxidized.

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25 days ago
Which structural formula correctly represents an organic compound
Alekssandra [3086]
A skeletal formula is usually used for organic compounds
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15 days ago
An unknown liquid has a mass of 4.25 × 108 mg and a volume of 0.250 m3. what is the density of the liquid in units of g/ml?
VMariaS [2998]
Density is calculated as mass divided by volume.
  Step one:
Convert m³ to ml.
1 m³ = 1,000,000 ml
0.250 m³ x 1,000,000 = 250,000 ml
  Step two: Convert mg to g.
1 mg = 0.001 g, hence 4.25 x 10^8 mg equals 0.459 g.
Consequently, the density comes out to be 0.459 g/250,000 = 1.836 x 10^-6 g/ml.
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