Consider the reaction below. 2H2O 2H2 + O2 How many moles of hydrogen are produced when 6.28 mol of oxygen form?

Answer:

Explanation:

Diethyl malonate possesses greater acidity compared to monocarbonyl substances (pKa=13) because its alpha hydrogens are linked to two carbonyl groups. Consequently, the malonic ester can be readily changed into its enolate ion by reacting it with sodium ethoxide in ethanol. When the malonic ester undergoes alkylation, a hydrogen atom in the alpha position becomes acidic, permitting another round of alkylation to yield a dialkylated malonic ester.

In this scenario, when diethyl malonate interacts with urea in the presence of sodium ethoxide base, the second alkylation step occurs within the molecule, producing a cyclic compound known as barbituric acid.

Response: Option A) The lattice energy rises as cations become smaller, as demonstrated by LiF and KF.

Clarification: It has been observed that the lattice energy is largely determined by two primary factors regarding ionic solids:

i) The ionic charges - An increase in the charge of the ions corresponds to an increase in lattice energy.

and

ii) The size or radius of the ions - As the ionic size grows, the lattice energy diminishes accordingly.

Therefore, in this context, the latter factor is evident. Thus, it can be concluded that as cation sizes decrease among ionic solids, the lattice energy increases.

Answer:

15.71g

Explanation:

The combustion equation that applies to hydrocarbons is

CxHy + (x+y/4) O2 = xCO2 + (y/2) H2O

In the case of octane, C8H18:

C8H18 + ( 8 + 18/4 ) O2 = 8CO2 + 9H2O

C8H18 + 50/4 O2 = 8CO2 + 9H2O

C8H18 + 25/2 O2 = 8CO2 + 9H2O

2C8H18 + 25 O2 = 16 CO2 + 18H2O (this is the balanced equation)

From this balanced reaction,

2 x 22.4 L of octane generates 16 [ 12 + (16 x 2)] of carbon dioxide

That means,

44.8 L of octane generates 704g of carbon dioxide

Thus, for 1L of octane, it produces 1 L x 704g/44.8 L = 15.71g of carbon dioxide

Consequently, 15.71g of carbon dioxide is produced from the complete combustion of 1 L of octane.

Response: The rate constant at 525 K is,

Rationale:

Based on the Arrhenius equation,

or,

where,

= rate constant when =

= rate constant when =?

= activation energy for the process =

R = gas constant = 8.314 J/mole.K

= initial temperature = 701 K

= final temperature = 525 K

Substituting the provided values into this formula yields:

Thus, the rate constant at 525 K is,