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1 month ago

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During a titration the following data were collected. A 20.0 mL portion of solution of an unknown acid HX was titrated with 2.0

M KOH. It required 60.0 mL of the base to neutralize the sample. What is the molarity of the acid HX?

1 answer:

lions [2.9K]1 month ago

8 0

The concentration of acid HX is established at 6.0 M. Calculating the moles of KOH neutralizing the acid yields 0.12 moles KOH. Subsequently, converting this to the moles of acid results in 0.12 moles HX. Thus, the molarity of HX remains 6.0 M.

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A sample of solid naphthalene is introduced into an evacuated flask. Use the data below to calculate the equilibrium vapor press

Tems11 [2777]

Answer: The vapor pressure of naphthalene within the flask remains at $2.906\times 10^{-4}$ atm.

Explanation:

The transformation from solid naphthalene to its gaseous form follows the equilibrium reaction:

$C_{10}H_8(s)\rightleftharpoons C_{10}H_8(g)$

The formula employed to determine the enthalpy change for the reaction is:

$\Delta H^o_{rxn}=\sum [n\times \Delta H^o_f(product)]-\sum [n\times \Delta H^o_f(reactant)]$

The formula for calculating the enthalpy change regarding the aforementioned reaction is:

$\Delta H^o_{rxn}=(1\times \Delta H^o_f_{(C_{10}H_8(g))})-(1\times \Delta H^o_f_{(C_{10}H_8(s))})$

The provided information includes:

$\Delta H^o_f_{(C_{10}H_8(s))}=78.5kJ/mol\\\Delta H^o_f_{(C_{10}H_8(g))}=150.6kJ/mol$

Substituting the values into the previous equation produces:

$\Delta H^o_{rxn}=(1\times 150.6)-(1\times 78.5)=72.1kJ/mol$

The formula utilized to compute Gibbs free energy change is of a reaction:

$\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f(product)]-\sum [n\times \Delta G^o_f(reactant)]$

The equation for the enthalpy change for the reaction is:

$\Delta G^o_{rxn}=(1\times \Delta G^o_f_{(C_{10}H_8(g))})-(1\times \Delta G^o_f_{(C_{10}H_8(s))})$

The given factors include:

$\Delta G^o_f_{(C_{10}H_8(s))}=201.6kJ/mol\\\Delta G^o_f_{(C_{10}H_8(g))}=224.1kJ/mol$

By inserting values from the above equation, we arrive at:

$\Delta G^o_{rxn}=(1\times 224.1)-(1\times 201.6)=22.5kJ/mol$

For the calculation of $K_1$ (at 25°C) regarding the provided value of Gibbs free energy, the following relationship is applied:

$\Delta G^o=-RT\ln K_1$

where,

$\Delta G^o$ = Gibbs free energy = 22.5 kJ/mol = 22500 J/mol (Conversion factor: 1kJ = 1000J)

R = Gas constant = $8.314J/K mol$

T = temperature = $25^oC=[273+25]K=298K$

$K_1$ = equilibrium constant at 25°C =?

Inserting values into the above equation yields:

$22500J/mol=-(8.314J/Kmol)\times 298K\times \ln K_1\\\\K_1=1.14\times 10^{-4}$

To determine the equilibrium constant at 35°C, we refer to the equation proposed by Arrhenius, which states:

$\ln(\frac{K_2}{K_1})=\frac{\Delta H}{T}(\frac{1}{T_1}-\frac{1}{T_2})$

where,

$K_2$ = Equilibrium constant at 35°C =?

$K_1$ = Equilibrium constant at 25°C = $1.14\times 10^{-4}$

$\Delta H$ = Enthalpy change of the reaction = 72.1 kJ/mol = 72100 J

R = Gas constant = $8.314J/K mol$

$T_1$ = Initial temperature = $25^oC=[273+25]K=298K$

$T_2$ = Final temperature = $35^oC=[273+35]K=308K$

By plugging values into the equation above, we obtain:

$\ln(\frac{K_2}{1.14\times 10^{-4}})=\frac{72100J/mol}{8.314J/K.mol}(\frac{1}{298}-\frac{1}{308})\\\\K_2=2.906\times 10^{-4}$

In order to calculate the partial pressure of naphthalene at 35°C, we utilize the equation for $K_p$ , which is:

$K_p=\frac{p_{C_{10}H_8(g)}}{p_{C_{10}H_8(g)}}=p_{C_{10}H_8(g)$

The partial pressure of the solid phase is considered to be 1 at equilibrium.

Therefore, the value for $K_2$ will equal $K_p$

$p_{C_{10}H_8}=2.906\times 10^{-4}$

Consequently, the partial pressure of naphthalene at 35°C is $2.906\times 10^{-4}$ atm.

3 0

1 month ago

A 0.784 g sample of magnesium is added to a 250 ml flask and dissolved in 150 ml of water. magnesium hydroxide obtained from the

Anarel [2989]

Although multiple values are given, our focus is on HCl.

<span>We have 215 mL (0.215 L) of 0.300 M HCl fully consumed in the reaction. It's important to recall that the number of moles is found by multiplying volume by molarity:</span>

moles = 0.215 L × 0.300 M

<span>moles = 0.0645 moles of HCl</span>

4 0

3 months ago

Salt solutions can be __________ to give solid salts. What word completes this sentence?

alisha [2963]

Answer:

evaporated

Explanation:

Once the solution evaporates, only salt will remain, as the sole other component in the solution is water.

7 0

2 months ago

Which of the following reactions is a redox reaction? (a) K2CrO4 + BaCl2 → BaCrO4 + 2KCl (b) Pb2+ + 2Br- → PbBr2 (c) Cu + S → Cu

castortr0y [3046]

(c) Cu + S → CuS is classified as a redox reaction

Explanation:

The following reactions are presented:

(a) K₂CrO₄ + BaCl₂ → BaCrO₄ + 2 KCl

(b) Pb²⁺ + 2 Br⁻ → PbBr₂

(c) Cu + S → CuS

Reaction (c) represents a redox reaction, as the oxidation states of the elements are changing. In this case:

Cu + S → CuS

In its elemental form, Cu has an oxidation state of 0, while in CuS (copper sulfide), its oxidation state changes to +2.

Similarly, S in its elemental form has an oxidation state of 0 and is -2 in CuS (copper sulfide).

Learn more about:

redox reactions

7 0

2 months ago