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borishaifa
15 days ago
14

Using the standard reduction potentials listed in appendix e, calculate the equilibrium constant for the reaction at 298 k: 3 ce

4+ (aq) + bi (s) + h2o (l) → 3 ce3+ (aq) + bio+ (aq) + 2 h+ (aq)
Chemistry
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A specific amount of energy is emitted when excited electrons in an atom in a sample of an element return to the ground state.Th
castortr0y [3046]
The answer is C. The specific amount of energy released when excited electrons fall back to the ground state produces an emission spectrum. That energy is emitted as photons with precise wavelengths corresponding to the energy differences between levels. Because each element yields a characteristic set of wavelengths, the emission spectrum can be used to identify the element in the sample.
5 0
2 months ago
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A water tank can hold 1 m3 of water. When it’s empty, how much liters is needed to refill it?
Alekssandra [3086]

Response: 1000

Rationale: because 5 cubic meters equals 5000 liters

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2 months ago
What is the density (in g/L) of a gas with a molar mass of 16.01 g/mol at 1.75 ATM and 337 K?
Anarel [2989]
To solve for density, you can use the formula--> Density= PM/ RT, where P stands for pressure, M for molar mass, R represents the gas constant, and T is temperature. 

P= 1.75 atm
M= 16.01 g/ mol
R= 0.0821 atm·L/ mol·K
T=337 k

Thus, the density calculation becomes: density= (1.75 x 16.01)/ (0.0821 x 337)= 1.01 g/L
8 0
1 month ago
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PART A: Use the following glycolytic reaction to answer the question. If the concentration of DHAP is 0.125 M and the concentrat
alisha [2963]

Answer:

For A: The change in free energy for the reaction is -5339.76 J/mol

For B: Free energy change is expressed in kJ/mol

For C: The forward reaction favors progression, while the reverse reaction does not.

Explanation:

Regarding the specified chemical reaction:

DHAP\rightleftharpoons G_3P

  • For A:

The relationship between standard Gibbs free energy and equilibrium constant is as follows:

\Delta G^o=-RT\ln K_{eq}

The free energy change can be calculated using the following equation:

\Delta G=\Delta G^o+RT\ln Q

Or,

\Delta G=-RT^o\ln K_{eq}+RT\ln Q

where,

\Delta G = Change in free energy

R = Gas constant = 8.314J/K mol

T^o = standard temperature = 25^oC=[273+25]K=298K

T = temperature of the cell = 37^oC=[273+37]K=310K

K_[eq} = equilibrium constant = 5.4\times 10^{-2}

Q = reaction quotient = \frac{[G_3P]}{[DHAP]}

[G_3P] = 0.06 M

[DHAP] = 0.125 M

Substituting the values into the equation yields:

\Delta G=[-(8.314J/mol.K\times 298K\times \ln (5.4\times 10^{-2}))]+[(8.314J/mol.K\times 310K\times \ln (\frac{0.06}{0.125}))]\\\\\Delta G=-[-7231.46]+[-1891.7]=-5339.76J/mol

Thus, the change in free energy for the reaction is -5339.76 J/mol

  • For B:

To convert the free energy change to kilojoules, we apply the conversion factor:

1 kJ = 1000 J

So, -5339.76J/mol\times \frac{1kJ}{1000J}=-5.34kJ/mol

Consequently, the free energy change's units are kJ/mol

  • For C:

For spontaneity in the reaction, the Gibbs free energy must be negative. However, the calculations indicate a positive Gibbs free energy, leading to the conclusion that the reaction is not spontaneous.

The free energy change of the reaction is negative.

Consequently, the forward reaction is favored and the reverse reaction is not favored.

8 0
2 months ago
You want to prepare a solution with a concentration of 200.0μM from a stock solution with a concentration of 500.0mM. At your di
lorasvet [2795]

Answer:

1) This dilution plan will yield a 200μM solution.

2) This dilution plan will not yield a 200μM solution.

3) This dilution plan will not yield a 200μM solution.

4) This dilution plan will yield a 200μM solution.

5) This dilution plan will yield a 200μM solution.

Explanation:

Convert the initial molarity into molar form as shown.

500mM = 500mM \times (\frac{1M}{1000M})= 0.5M

Let's examine the following serial dilution processes.

1)

Dilute 5.00 mL of the stock solution to 500 mL. Then take 10.00 mL of this new solution and dilute it further to 250 mL.

Concentration of 500 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{500 mL}= 5 \times 10^{-3}M

10 mL of this solution is further diluted to 250 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(5 \times 10^{-3}M)(10.0mL)}{250 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

2)

Dilute 5.00 mL of the stock solution to 100 mL. Then take 10.00 mL of this new solution and dilute to 1000 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5.00mL)}{100 mL}= 2.5 \times 10^{-2}M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(2.5 \times 10^{-2}M)(10.0mL)}{1000 mL}= 2.5 \times 10^{-4}M

Convert μM:

2.5 \times 10^{-4}M = (2.5 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 250 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

3)

Dilute 10.00 mL of the stock solution to 100 mL, followed by diluting 5 mL of that new solution to 100 mL.

Concentration of 100 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{100 mL}= 0.05M

5 mL of this solution is diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.05M)(5mL)}{1000 mL}= 0.25 \times 10^{-4}M

Convert μM:

0.25 \times 10^{-4}M = (0.25 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 25 \mu M

Thus, this dilution scheme will not yield a 200μM solution.

4)

Dilute 5 mL of the stock solution to 250 mL. Then take 10 mL of this new solution and further dilute it to 500 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(5mL)}{250 mL}= 0.01M

10 mL of this solution is further diluted to 500 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.01M)(10mL)}{500 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

5)

Dilute 10 mL of the stock solution to 250 mL. Then take another 10 mL of this new solution and dilute it to 1000 mL.

Concentration of 250 mL solution:

M_{2}= \frac{M_{1}V_{1}}{V_{2}}= \frac{(0.5M)(10mL)}{250 mL}= 0.02M

10 mL of this solution is further diluted to 1000 mL

M_{final}= \frac{M_{2}V_{2}}{V_{final}}= \frac{(0.02M)(10mL)}{1000 mL}= 2 \times 10^{-4}M

Convert μM:

2 \times 10^{-4}M = (2 \times 10^{-4}M)(\frac{1 \mu M}{10^{-6}M})= 200 \mu M

Thus, this dilution scheme will yield a 200μM solution.

7 0
2 months ago
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