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CaHeK987
1 month ago
13

The decomposition of nitramide, O2NNH2, in water has the chemical equation and rate law O2NNH2(aq)⟶N2O(g)+H2O(l)rate=k[O2NNH2][H

+] A proposed mechanism for this reaction is O2NNH2(aq)⥫⥬=k−1k1O2NNH−(aq)+H+(aq)(fast equilibrium) O2NNH−(aq)−→k2N2O(g)+OH−(aq)(slow) H+(aq)+OH−(aq)−→k3H2O(l)(fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism?
Chemistry
1 answer:
KiRa [2.9K]1 month ago
7 0

Answer:

It can be inferred that the reaction's third step occurs very rapidly, thus it does not influence the rate law.

Explanation:

Refer to the solution in the Word document attached.

Download docx
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the image above shows a chamber with a fixed volume filled with gas at a pressure of 1560 mmHg and a temperature of 445.0 K. If
VMariaS [2998]

Answer:

The new gas pressure within the chamber registers at 1,093.75 mmHg

Explanation:

The Gay-Lussac Law establishes a relationship between a gas's pressure and temperature when volume remains constant. This principle asserts that gas pressure is directly tied to its temperature: as temperature increases, pressure rises, and conversely, as temperature falls, pressure also diminishes. Therefore, the Gay-Lussac law can be depicted mathematically as:

\frac{P}{T} =k

Given an initial and final state of gas, we can apply the following formula:

\frac{P1}{T1} =\frac{P2}{T2}

In this scenario:

  • P1= 1560 mmHg
  • T1= 445 K
  • P2=?
  • T2= 312 K
<psubstituting:>

\frac{1560 mmHg}{445 K} =\frac{P2}{312 K}

Calculating:

P2=\frac{1560 mmHg}{445 K} *312K

P2=1,093.75 mmHg

The new gas pressure inside the chamber is 1,093.75 mmHg

</psubstituting:>
7 0
1 month ago
A mass of 5.4 grams of aluminum (al) reacts with an excess of copper (ii) chloride (cucl2) in solution, as shown below. 3cucl2 2
eduard [2782]

Answer:

The mass of copper generated is 19.07g

Explanation:

Let's write out the chemical equation;

3CuCl2 + 2Al → 2AlCl3 + 3Cu

3:   2:   2: 3

After confirming that the reaction is balanced, we can continue.

The problem asks for the mass of Cu produced from 5.4g of Al reacting.

Based on the equation, what is the relation between Al and Cu?

2 moles of Al would yield 3 moles of Cu

Expressing this in mass terms, we find;

mass = number of moles * molar mass

Mass of Aluminium = 2 * 26.98 = 53.98 g

Mass of Copper = 3 * 63.546 = 190.638g

This indicates that;

53.98 g of Al would react to create 190.638g of Cu

So, how much Cu would result from 5.4 g of Al?

This leads us to;

53.98 = 190.638

5.4 = x

By cross multiplication, we determine;

x = (190.638 * 5.4) / 53.98

x = 19.07 g

The mass of copper created is 19.07g

8 0
14 days ago
According to the storage ladder protocol, raw meat should be stored on shelves based on its? A.Minimum internal cooking temperat
Anarel [2989]

Response:

D. Maximum internal cooking temperature

Clarification:

Per the Storage Ladder Protocol, proper rules must be followed when storing food in the refrigerator. Prepared dishes belong on the highest shelf; fruits and vegetables are positioned on the next; fish and seafood go on the third; beef and pork are kept on the fourth; ground meat is stored on the fifth; and poultry items sit on the bottom shelf. This illustrates that ground beef should be placed above chicken. A diagram is included below for optimal storage order explanation.

7 0
26 days ago
Read 2 more answers
An unknown compound, X is thought to have a carboxyl group with a pKa of 2.0 and another ionizable group with a pKa between 5 an
alisha [2963]

Answer:

7.3

Explanation:

Using the Henderson Hasselbalch equation, one can determine the pH or pOH of a solution via its pKa. Remember, pH = -log[H^{+}], and pKa = -logKa, where Ka denotes the acid's equilibrium constant.

The Henderson Hasselbalch formula:

pH = pKa - log \frac{[HA]}{[A^{-}]}

In this context, acid X possesses two ionic forms: the carboxyl group and an alternative form. Initially, we have 0.1 mol/L of acid in 100 mL, which gives:

n1 = (0.1 mol/L)×(0.1 L) = 0.01 mol

Upon dissociation, it yields 0.005 mol of the carboxyl form and 0.005 mol of the other form with stoichiometry assumed constant.

Introducing NaOH at a concentration of 0.1 mol/L and 75 mL, the moles of OH^- become:

n2 = (0.1 mol/L)×(0.075 L) = 0.0075 mol

Thus, 0.0075 mol of OH^- reacts with 0.005 mol of the carboxyl form, leading to 0.0025 mol of OH^-, which in turn reacts with 0.005 mol of the alternating group, leaving 0.0025 mol of the latter.

The new solution’s volume is 175 mL, but the concentrations of both forms remain unchanged in volume, so we can utilize the moles in the equation.

<pNote, the moles of the acid form remain 0.01 mol as it doesn’t undergo reaction!

Thus, we arrive at:

6.72 = pKa - log \frac{0.01}{0.0025}

6.72 = pKa - log 4

pKa - log 4 = 6.72

pKa = 6.72 + log 4

pKa = 6.72 + 0.6

pKa = 7.3

8 0
1 month ago
Compare the system (still at 50 °C) with a volume of 1.0 L and with 3.0 L. What is the total amount of gas (mol) present in the
Anarel [2989]
In the container with a volume of 1 L, the total amount of gas is 0.0446 moles, whereas in a 3 L container, it is 0.1334 moles. Explanation: Since 1 mole of gas occupies 22.4 liters, to find the total gas quantity present in both the 1 L and 3 L containers, we divide the respective volumes by the reciprocal of 22.4 liters, leading to the determination of the moles of gas at each volume. Hence for 1 L, there are 0.0446 moles, and for 3 L, it is calculated to be 0.1334 moles. Thus, it can concluded that the number of moles increases with a rise in volume or expansion of gas.
3 0
28 days ago
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