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Colt1911
8 days ago
13

Carbonic acid, H2CO3, has two acidic hydrogens. A solution containing an unknown concentration of carbonic acid is titrated with

potassium hydroxide. It requires 20.0 mL of 3.840 M KOH solution to titrate both acidic protons in 50.2 mL of the carbonic acid solution.
1. Write a balanced net ionic equation for the neutralization reaction. Include physical states.
2. Calculate the molarity of the carbonic acid solution.
Chemistry
1 answer:
KiRa [971]8 days ago
6 0

Answer:

1) The net ionic equation:

2H^+(aq)+2OH^-(aq)\rightarrow 2H_2O(l)

2) The molarity of the carbonic acid solution equals 0.765 M.

Explanation:

1) In aqueous carbonic acid, both carbonate ions and hydrogen ions exist:

H_2CO_3(aq)\rightarrow 2H^+(aq)+CO_3^{2-}(aq)..[1]

In potassium hydroxide solution, potassium ions and hydroxide ions are found:

KOH(aq)\rightarrow K^+(aq)+OH^{-}(aq)..[2]

In potassium carbonate solution, potassium ions and carbonate ions are present:

K_2CO_3(aq)\rightarrow 2K^+(aq)+CO_3^{2-}(aq)..[3]

H_2CO_3(aq)+2KOH(aq)\rightarrow K_2CO_3(aq)+2H_2O(l)

From these:[1], [2], and [3]:

2H^+(aq)+CO_3^{2-}(aq)+2K^+(aq)+2OH^{-}(aq)\rightarrow 2K^+(aq)+CO_3^{2-}(aq)+H_2O(l)

To formulate the net ionic equation, eliminate common ions on both sides:

2H^+(aq)+2OH^-(aq)\rightarrow 2H_2O(l)

2)

For determining acid concentration, utilize the equation from the neutralization reaction:

n_1M_1V_1=n_2M_2V_2

In which,

n_1,M_1\text{ and }V_1 indicates the n-factor, molarity and volume related to acid represented as H_2CO_3.

n_2,M_2\text{ and }V_2 indicates n-factor, molarity and volume concerning the KOH base.

Provided information includes:

n_1=2\\M_1=?\\V_1=50.0 mL\\n_2=1\\M_2=3.840 M\\V_2=20.0 mL

By plugging in these values to the equation, we find:

M_1=\frac{1\times 3.840 M\times 20.0 mL}{2\times 50.2 mL}=0.765 M

The molarity of the carbonic acid solution is found to be 0.765 M.

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Answer:

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Explanation:

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Here, R corresponds to the lithium atom's radius. Since the radius is provided in picometers, we first convert it into meters.

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The full question can be found in the image linked to this response.

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