Answer: The accurate option is a.
The nitrate ion concentration in the final mixture is approximately 0.48056 M.
Explanation:


Calculating nitrate ions from 35.0 mL of 0.255 M nitric acid:

Calculated moles of nitric acid = 0.008925 mol
1 mole of nitric acid yields 1 mole of nitrate ions,
Therefore, 0.008925 moles of nitric acid will produce 0.008925 moles of nitrate ions.
Resulting in moles of nitrate in 35.00 mL of the solution = 0.008925 mole..(1)
Calculating nitrate ions from 45.0 mL of 0.328 M magnesium nitrate:


Calculated moles of magnesium nitrate = 0.01476 mol
1 mole of magnesium nitrate generates 2 moles of nitrate ions,
Hence, 0.01476 moles of magnesium nitrate results in:
of nitrate ions
Thus, moles of nitrate ions in 45.00 mL of solution = 0.02952 mol...(2)
Total moles of nitrate ions =
0.008925 mol+0.02952 mol = 0.038445 mol
Total volume after mixing = 35.00 mL+ 45.00 mL =
80.00 mL = 0.080 L
Final solution's nitrate ion concentration:
