Compounds A and B are colorless gases obtained by combining sulfur with oxygen. Compound A results from combining 6.00 g of sulf

Answer:

A - Increase (R), Decrease (P), Decrease(q), Triple both (Q) and (R)

B - Increase(P), Increase(q), Decrease (R)

C - Triple (P) and cut (q) down to a third

Explanation:

According to the principle of Le Chatelier, when a system reaches equilibrium and a change is introduced, the system will respond to counteract that change.

Since P and Q are reactants, raising the amount of either one or both without a proportional rise in R (which is a product) will cause the equilibrium to move towards the right. Similarly, if R decreases while P and Q remain constant, this too will push the equilibrium to the right. Thus, Increase(P), Increase(q), and Decrease(R) will lead to a rightward shift in the equilibrium.

Conversely, raising R without increasing P and Q will draw the equilibrium to the left. Likewise, cutting down P and/or Q without a similar reduction in R will shift the equilibrium leftward. Therefore, Increase(R), Decrease(P), Decrease(q), and triple both (Q) and (R) will shift the equilibrium to the left.

If there are equivalent changes in P and Q, with R remaining unchanged, then the equilibrium remains stationary. So, tripling (P) while reducing (q) to one third will not alter the equilibrium.

Answer:

Explanation:

This scenario is unrealistic since Al(OH)₃ is not soluble in water.

The question consists of two parts:

A. Stoichiometry — where we determine volumes, masses, and moles for the products

B. Calorimetry — where we assess the enthalpy of the reaction.

A. Stoichiometry

1. Determine the volume of Al(OH)₃

(a) The balanced chemical equation:

                 2Al(OH)₃ + 3H₂SO₄ ⟶ Al₂(SO₄)₃ + 6H₂O

M/V:            66.667

c/mol·L⁻¹:   4.000       3.000

(b) Moles of H₂SO₄

(c) Moles of Al(OH)₃

The molar ratio stands at 2 mmol Al(OH)₃: 3 mmol H₂SO₄

(d) Volume of Al(OH)₃

B. Calorimetry

This reaction has two energy exchanges.

q₁ = heat from the reaction

q₂ = heat used to heat the calorimeter

 q₁ + q₂ = 0

nΔH + mCΔT = 0

Data:

Moles of Al₂(SO₄)₃ = 0.066 667 mol

C = 1.10 J°C⁻¹g⁻¹

T_initial = 22.3 °C

T_final = 24.7 °C

Calculations

(a) Mass of solution

Assume solutions are as dense as water (though not realistic).

Mass of sulfuric acid solution            =   66.667 g 

Mass of aluminium hydroxide solution =  50.000    

                                             TOTAL =  116.667 g

(b) ΔT

ΔT = T_final - T_initial = 24.7 °C - 22.3 °C = 2.4°C

(c) ΔH

This result appears nonsensical, but it is derived from your given figures.

Answer:

180.56 kilojoules of heat energy is extracted when 1.00 kg of freon-11 evaporates.

Explanation:

The molar mass of freon-11 is 137.35 g/mol

The enthalpy of vaporization for freon-11 is 24.8 kJ/mol at its normal boiling point of 24°C. Given that,

Mass of freon-11 evaporated = 1.00 kg = 1000 g

Moles of freon-11 evaporated can be calculated as

The energy removed in the form of heat when 1.00 kg of freon-11 vaporizes is:

The balanced equation is:

NaCH₃COO + HCl → NaCl + HCH₃COO

Make 

N₀ signifies the quantity of C-14 atoms per kg of carbon in the original sample at time = 0 seconds, when the carbon composition matched that in today’s atmosphere. As time progresses to ts, the number of C-14 atoms per kg declines to N, due to radioactive decay. λ indicates the decay constant.
Hence, we have N = N₀e - λt, which is the equation for radioactive decay. Rearranging gives us N₀/N = e λt, or In(N₀/N) = - λt, which becomes equation 1.
The sample contains mc kg of carbon, leading to an activity measured as A/mc decay per kg. The variable r represents the initial mass of C-14 in the sample at t=0 relative to the total mass of carbon which is calculated as [(total number of C-14 atoms at t = 0) × ma] / total mass of carbon. Thus, N₀ equates to r/ma, which becomes equation 2.
The activity of the radioactive element is directly related to the atom count at the moment. The activity equation A = dN/dt = λ(N) indicates that: A = λ₁(N × mc). Rearranging provides N = A / (λmc), represented in equation 3.
By integrating equations 2 and 3, we can solve for t yielding
t = (1/λ) In(rλmc/m₀A).