Answer:
Explanation:
The relationship between the new temperature scale and the absolute temperature scale is defined as follows
Aw = 2 K
for K = 273.15 (the freezing point of water on the absolute scale)
Aw = 2 x 273.15 = 546.3 K
Each division of the new scale is equivalent to half that of each division on the absolute scale
each division of the new scale is minimal.
The value of R = 8.314 J per mole per K
Here, per K corresponds to 2Aw
Hence, the value of R in the new scale = 8.314/2 J per mole per Aw
= 4.157 J per mole per Aw
k = R / N
= 4.157 / 6.02 x 10²³
= .69 x 10⁻²³
= 6.9 x 10⁻²⁴ J per molecule per Aw .
Answer:
Explanation:
Diethyl malonate possesses greater acidity compared to monocarbonyl substances (pKa=13) because its alpha hydrogens are linked to two carbonyl groups. Consequently, the malonic ester can be readily changed into its enolate ion by reacting it with sodium ethoxide in ethanol. When the malonic ester undergoes alkylation, a hydrogen atom in the alpha position becomes acidic, permitting another round of alkylation to yield a dialkylated malonic ester.
In this scenario, when diethyl malonate interacts with urea in the presence of sodium ethoxide base, the second alkylation step occurs within the molecule, producing a cyclic compound known as barbituric acid.
Explanation:
Initial moles of ethanoic acid = 0.020 mol
At equilibrium, half of the ethanoic acid molecules have reacted.
Thus, moles of ethanoic acid reacted = 0.020 mol * (50% / 100%)
= 0.010 mol
Moles of ethanoic acid remaining = 0.020 mol - 0.010 mol = 0.010 mol
The moles of product
gas formed are determined as follows:
0.010 mol CH3COOH * (1 mol
/ 2 mol CH3COOH)
= 0.005 mol 
Consequently, the total moles of gas present in the vessel at equilibrium are 0.010 mol CH3COOH and 0.005 mol 
Total gas moles at equilibrium = 0.010 mol + 0.005 mol = 0.015 mol
Next, let’s determine the pressure:
0.020 mol of gas has a pressure of 0.74 atm; so under the same conditions, we find the pressure exerted by 0.015 mol of gas:
P1/n1 = P2/n2
P2 = P1*(n2 / n1)
= 0.74 atm * (0.015 mol / 0.020 mol)
= 0.555 atm
Answer:
When HBCG and BCG^- are at the same concentration, the resulting color is green. This green shade initially becomes visible at a pH of 3.8.
Explanation:
HBCG serves as an indicator formed by dissolving solids in ethanol.
Since
Ka=[BCG−][H3O+][HBCG] When [BCG-] equals [HBCG], it follows that Ka = [H3O+].
<pWith a pH of 3.8,<pKa= [H3O+] = -antilog pH = -antilog (3.8)
Ka= 1.58 ×10^-4
<span>Some solutions demonstrate colligative properties, which rely on the quantity of solute in a solvent. To find the elevation in boiling point, we use the formula:
</span><span>ΔT(boiling point) =
(Kb)mi
where Kb represents a constant, m is the solution's molality, and i is the van't Hoff factor.
From the provided information, we can easily determine i as follows:
</span>ΔT(boiling point) = (Kb)mi
103.45 - 100 = (0.512)3.90i
i = 1.73 <-------van't Hoff factor